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Equilibrium Test - 43

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Equilibrium Test - 43
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  • Question 1
    1 / -0
    Sodium chloride is purified by passing hydrogen chloride gas in an impure solution of sodium chloride. It is base on
    Solution
    $$\text{Purification of NaCl by the passage of HCl through brine is based on the common ion effect.}$$
    $$\text{HCl is a strong electrolyte and provides an ion }(Cl^−)\text{ that is common to that provided by the weak electrolyte.}$$$$\text{Thus, the ionization of weak electrolytes is suppressed.}$$
  • Question 2
    1 / -0
    Which one is buffer solution
    Solution
    [Normal salt+acidic salt] is a buffer solution.

    $$\underset {normal\ salt}{[PO_{3}^{3-}]} \underset {acidic\ salt}{[H_{2}PO_{4}^{-}]}$$

    Option B is correct.
  • Question 3
    1 / -0
    The degree of dissociation in a weak electrolyte increases________
    Solution
    In weak electrolyte the degree of dissociation is very small. So it increases with increasing dilution.

    Option A is correct.
  • Question 4
    1 / -0
    Which one of the following is not a buffer solution?
    Solution
    Buffer solutions can be obtained by mixing a weak acid with its salt formed with a strong base or by mixing a weak base with its salt formed with a strong acid.

    Because $$HClO_4$$ is a strong acid. While buffer is a mixture of weak acid and their salt.
  • Question 5
    1 / -0
    Which of the following will produce a buffer solution when mixed in equal volumes?
    Solution
    $$0.1 mol\  dm^{-3}$$ $$NH_{4}OH$$ and $$0.05 mol\  dm^{-3}$$ $$HCl$$.
    As a mixture of ammonium chloride and ammonium hydroxide acts as a buffer around pH $$9.25$$.
  • Question 6
    1 / -0
    At $$25^{o}C$$ the $$pH$$ value of a solution is $$6$$. The solution is
    Solution
    pH value of  0-7 is acidic 
    ph=7 nutral
    pH 7- 14 basic
  • Question 7
    1 / -0
    A system at equilibrium is described by the equation of fixed temperature $$T$$.
    $$SO_2Cl_2(g) \rightleftharpoons SO_2(g) +Cl_2(g)$$
    What effect will an increases in the total pressure caused by a decrease in volume have on the equilibrium?
    Solution
    Concentration of all gases increases and equilibrium shifts towards less no. of moles but new equilibrium concentration of every gas would be higher than earlier.
  • Question 8
    1 / -0
    A solution that resists changes in pH upon the addition of a small amount of strong acid or strong base known as_____
    Solution
    Because buffer solution have a constant $$pH$$.
  • Question 9
    1 / -0
    Assertion: Equilibrium constant of a reaction increases if temperature is increased.
    Reason: The forward reaction becomes faster with increase of temperature.
    Solution
    Effect of temperature on equilibrium constant $$K$$ depends upon whether the reaction is exothermic or endothermic.

    hence If both Assertion and Reason are false.
  • Question 10
    1 / -0
    The reaction, $$SO_2+Cl_2\rightleftharpoons SO_2 Cl_2$$ is exothermic and reversible. A mixture of $$SO_2(g). Cl_2(g)$$ and $$SO_2 , Cl_2(g)$$ is equilibrium in a closed container. Now a certain quantity of extra $$SO_2$$ is introduced into the container, the volume remaining the same. Which of the following is/are true?
    Solution
    $$SO_2+Cl_2 \rightleftharpoons SO_2Cl_2 +$$Heat. On adding $$SO_2$$ the equilibrium will shift forward i.e, more heat will be evolved. So temperature will increase.
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