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Redox Reactions Test - 36

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Redox Reactions Test - 36
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  • Question 1
    1 / -0
    $$CrO_5$$ has structure as shown, The oxidation number of chromium in the compound is?

    Solution
    By looking the above structure we can observe that 4 oxygen atoms are linked by peroxide linkage. So there oxidation state is -1 as in peroxide.
    One oxygen atom is attached normally so its oxidation state is -2.
    So oxidation state of $$Cr$$ is $$x+4(-1)+(-2)=0,x=+6$$
  • Question 2
    1 / -0
    Oxidation number of Cl in $$CaOCl_2$$ is ____________.
    Solution
    In $$Ca(OCl)Cl$$, two $$Cl$$ atoms are in different oxidation state i.e., one $$Cl^{-}$$ in -1 oxidation state and other as $$OCl^{-}$$ in +1 oxidation state.

  • Question 3
    1 / -0
    The oxidation state of iodine in $$IPO_4$$ is:
    Solution
    Let oxidation state of iodine be x.
    $$x-3=0, x=+3$$,
    $$\because PO^{3-}_4$$ has combined oxidation number $$-3$$.
    $$\therefore x-3=0$$
    $$\therefore x=+3$$
    Thus oxidation state of iodine is +3.
  • Question 4
    1 / -0
    Find the oxidation number of V in $$Rb_4Na[HV_{10}O_{28}]$$.
    Solution
    Let oxidation state of $$V$$ is $$x$$ in $$Rb_4Na[HV_{10}O_{23}]$$
    $$H(1) + 1 + 1 + 10x - 2 (28) = 0$$
    $$6 + 10x - 56 = 0 $$
    $$10x = 50$$
    $$x = +5$$
  • Question 5
    1 / -0
    The oxidation state of the underlined element in the given compound is:
    $$\underline{C_{12}}H_{22}O_{11}$$
    Solution
    $$C_{12}H_{22}O_{11}$$= Sucrose
    $$\Rightarrow 12x+22 \times 1- 11 \times 2=0$$
    $$\Rightarrow 12x+22-22=0$$
    $$\Rightarrow x=0$$ .
  • Question 6
    1 / -0
    The oxidation state of the underlined element in the given compound is:
    $$Na_2[\ \underline{Fe}(CN)_5NO\ ]$$
    Solution
    Given compound $$Na_2[Fe(CN)_5NO]$$
    On dividing into ions we get
    $$[Fe(CN)_5NO]^{-3}$$ and $$3Na^{+1}$$
    $$\Rightarrow x+(-5)+0=-3$$
    $$\Rightarrow x= -3+5$$
    $$\Rightarrow x=+2$$ .
  • Question 7
    1 / -0
    The oxidation state of the underlined element in the given compound is:
    $$Ba_2\underline{Xe}O_2$$
    Solution
    $$Ba_2 Xe O_2$$
    $$\Rightarrow (+2)2+x+2(-2)=0$$
    $$\Rightarrow x=0$$

  • Question 8
    1 / -0
    The oxidation state of the underlined element in the given compound is:
    $$K_2\underline{Ta}F_7$$
    Solution
    $$K_2T_aF_1$$    Let oxidation state be $$x$$
    $$ 2 (+1) + x + T(-1) = 0$$
    $$x = +5$$
  • Question 9
    1 / -0
    In which compound among the following, carbon has a zero oxidation state?

    Solution
    $$\text{Sum of total oxidation state of all atoms } = \text{ Overall charge on the compound}.$$ 
    Oxidation state of $$Cl$$ is $$-1$$.Let oxidation state of $$C$$ be $$x$$.
    For $$CH_4$$, applying above formula, $$x+4(1)=0,\\x=-4.$$
    For $$CH_3Cl$$, applying above formula, $$x+3(1)+1(-1)=0,\\x=-2.$$
    For $$CH_2Cl_2$$, applying above formula, $$x+2(1)+2(-1)=0,\\x=0.$$
    For $$CCl_4$$, applying above formula, $$x+4(-1)=0,\\x=+4.$$
    $$\therefore$$ oxidation state is $$0$$ for $$C$$ in $$CH_2Cl_2$$
  • Question 10
    1 / -0
    The oxidation state of the underlined element in the given compound is:
    $$Na_2\underline{Mo}O_4$$
    Solution
    $$Na_2MnO_4$$   

     Let oxidation state of Mo be $$x$$ 

    $$ 2 (+1) + x + 4 (-2) = 0 $$

    $$x = +6$$
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