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Thermal Properties of Matter Test - 27

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Thermal Properties of Matter Test - 27
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  • Question 1
    1 / -0

    At a given temperature and pressure 64 gm of Oxygen and X gm of H$$_{2}$$ occupy the same volume. Then x= ......gm

    Solution
    Since they occupy same volume, the two gases should contain same number of molecules, i.e. they have same number of moles.
    Now 1 mole of oxygen = 32gm.
    Hence 64 gm = 2 mole of oxygen.
    $$\therefore $$ number of moles of hydrogen is 2.
    1 mole of hydrogen= 2gm
    Hence X= 4gm
  • Question 2
    1 / -0

    A one litre sphere and a two litre sphere are connected with a capillary tube of negligible volume. They contain an ideal gas at 27$$^{0}$$C at a pressure of 100cm of Hg. Keeping the temperature of one litre sphere constant at 27$$^{0}$$C, if temperature of two litre sphere is increased to 127$$^{0}$$C, then the final pressure is

    Solution
    Moles of gas in 1L sphere before increasing temperature $$=\dfrac{P_0 V}{RT}$$

    Moles of gas in 2L sphere before increasing temperature $$=\dfrac{P_0 (2V)}{RT}$$

    Moles of gas in 1L sphere after increasing temperature $$=\dfrac{PV}{RT}$$
    Moles of gas in 2L sphere after increasing temperature $$=\dfrac{P (2V)}{R(T+100)}$$
    Since the total number of moles remain the same,
    $$\dfrac{P_0V}{RT}+\dfrac{2P_0 V}{RT}=\dfrac{PV}{RT}+\dfrac{2PV}{R(T+100)}$$
    Hence, $$P=P_0 (\dfrac{3(T+100)}{3T+100})$$
    $$T=300K$$, $$P_0=100cm Hg$$
    $$\implies P=120cm Hg$$
  • Question 3
    1 / -0

    If pressure of an ideal gas contains in a closed vessel is increased by 0.5% the increase in temperature is 20k the initial temperature of the gas is

    Solution
    In this case,
    $$P_1 = P$$, $$P_2= 1.05P$$
    $${T_1} = T$$, $$T_2 = T+20$$
    Putting these values in $$\dfrac{P_1}{T_1}= \dfrac{P_2} {T_2}$$  we get, T = 400 or T = $$127^o$$C
  • Question 4
    1 / -0

    Two closed vessels of the equal volume contain air at 105kPa at 300K and are connected through a narrow tube. If one of the vessels is now maintained at 300K and the other at 400K then the pressure becomes.

    Solution
    In this case, let the initial pressure = P and final pressure = P'. Since (P/T) = constant, considering the system of two spheres of equal volume, we get,
    $$\dfrac{P}{300} + \dfrac{P}{300} = \dfrac{P'}{300} + \dfrac{P'}{400}$$
    here, P = 105k Pa
    Solving we get, $$P' = 120 kPa$$
      
  • Question 5
    1 / -0

    At the bottom of a lake where the temperature is $${7}^{0}\,C$$ the pressure is $$2.8$$ atmosphere. An air bubble of radius $$1\, cm$$ at the bottom rises to the surface. Where the temperature is $${27}^{0}\, C$$. The radius of the air bubble at the surface is

    Solution
     We know that, by gas law
    $$\dfrac { { P }_{ 1 }{ V }_{ 1 } }{ { T }_{ 1 } } =\dfrac { { P }_{ 2 }{ V }_{ 2 } }{ { T }_{ 2 } } $$
    $$\dfrac { 2.8{ \times V }_{ 1 } }{ 280 } =\dfrac { 1\times { V }_{ 2 } }{ 300 } $$
    $${ V }_{ 2 }=3{ V }_{ 1 }$$
    $$R\propto { V }^{ \dfrac { 1 }{ 3 }  }$$
    $$\therefore { R }_{ 2 }={ { 3 }^{ \dfrac { 1 }{ 3 }  }R }_{ 1 }$$
  • Question 6
    1 / -0

    During an experiment an ideal gas is found to obey an additional law V$$^{2}$$P= constant. The gas is initially at a temperature T and volume V. When it expands to a volume 2V, the temperature becomes

    Solution
    $${ V }^{ 2 }P=Constant\\ { V }^{ 2 }\left( \dfrac { RT }{ V }  \right) =Constant\\ VT=Constant\\ \therefore \dfrac { { V }_{ 1 } }{ { T }_{ 2 } } =\dfrac { { V }_{ 2 } }{ { T }_{ 1 } } \\ \\  { T }_{ 2 }=\dfrac { { T }_{ 1 }{ V }_{ 1 } }{ 2{ V }_{ 1 } } \\ \\ { T }_{ 2 }=\dfrac { { T }_{ 1 } }{ 2 } $$
  • Question 7
    1 / -0

    Two gases A and B having same pressure P, volume V and temperature T are mixed. if the mixture has volume and temperature as V and T respectively the pressure of mixture is

    Solution
    PV=nRT,
    Since gas has same volume they contain same number of molecules and hence same number of moles.
    Now since V and T remains same only n changes to 2n
    Hence P=2P
  • Question 8
    1 / -0

    A vessel is filled with an ideal gas at a pressure of 200 atm and is at a temperature of 27$$^{0}$$ C. One half of the mass of the gas is removed from the vessel and the temperature of the remaining gas is increased to 87$$^{0}$$ C. At this temperature,the pressure of the gas will be

    Solution
    $${ P }_{ 1 }{ V }_{ 1 }=\dfrac { { m }_{ 1 } }{ M } R{ T }_{ 1 }\\ { P }_{ 2 }{ V }_{ 2 }=\dfrac { { m }_{ 2 } }{ M } R{ T }_{ 2 }\\ { V }_{ 1 }={ V }_{ 2 },{ \quad 2m }_{ 2 }={ m }_{ 1 }\\ \dfrac { { P }_{ 1 } }{ { P }_{ 2 } } =\dfrac { { m }_{ 1 }{ T }_{ 1 } }{ { { m }_{ 2 }T }_{ 2 } } \\ { P }_{ 2 }=\dfrac { 360\times 200 }{ 300\times 2 } \\ \\ { P }_{ 2 }=120atm$$
  • Question 9
    1 / -0

    A gas is heated through $$1^{o}\ C$$ in a closed vessel. Its pressure is increased by $$0.4$$%. The initial emperature of the gas is

    Solution
    Since it is a closed system the volume remains constant.
    Hence,$$\dfrac { { P }_{ 1 } }{ { T }_{ 1 } } =\dfrac { { P }_{ 2 } }{ { T }_{ 2 } } $$
    $${ P }_{ 2 }=1.004{ P }_{ 1 }\\ \therefore { T }_{ 2 }=1.004{ T }_{ 1 }\\ but\quad { T }_{ 1 }+1={ T }_{ 2 }\\ \therefore { T }_{ 1 }=250K\\ { T }_{ 1 }=-{ 23 }^{ \circ  }$$
  • Question 10
    1 / -0

    A given amount of a gas is heated till the volume and pressure both increase by $$2\%$$ each the percentage change in temperature of the gas is  equal to nearly

    Solution
    $$\dfrac { dP }{ P } +\dfrac { dV }{ V } =\dfrac { dT }{ T } \\ Now\quad dP=0.02P,dV=0.02V\\ 0.02+0.02=\dfrac { dT }{ T } \\ \dfrac { dT }{ T } \times 100=4%=percentage\quad change\quad in\quad temperature$$
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