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Thermal Properties of Matter Test - 35

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Thermal Properties of Matter Test - 35
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  • Question 1
    1 / -0
    The temperature of the sun, if pressure is $$1.4 \times 10^9$$ atm, density is $$1.4 gcm^{-3}$$ and average molecular weight is 2, will be
    $$[Given\  R = 8.4  J  mol^{-1} K^{-1}]$$
    Solution
    $$PV = nRT     n = \displaystyle \frac{m}{M} $$ and $$\rho = \displaystyle \frac{m}{V}$$
    or
    $$\displaystyle T = \frac{PV}{nR} = \frac{PM}{\rho R}$$
    $$= \displaystyle \frac{1.4 \times 10^9 \times 1.01 \times 10^5 \times 2 \times 10^{-3}}{1.4 \times 10^3 \times 8.4}$$
    $$= 2.4 \times 10^7  K$$
  • Question 2
    1 / -0

    Directions For Questions

    An automobile tyre has volume $$0.015 m^3$$ on a cold day when temperature is $$5^o C$$ and atmospheric pressure is $$1.02\ atm$$. Under these conditions the gauge pressure is $$1.7\ atm\ (25\ lb/in^2)$$. After the car is driven on a highway for 30 minutes the temperature of the air in the tyres rises to $$45^oC$$ and volume to $$0.0159 m^3$$.

    ...view full instructions

    What is new gauge pressure?
    Solution
    $$\displaystyle \frac{p_1 V_1}{T_1} = \frac{p_2 V_2}{T_2}$$
    or $$\displaystyle P_2 = \frac{2.72 \times 150 \times 318}{278 \times 159}$$
    $$= 2.94 atm$$
    Gauge pressure $$= 2.94 - 1.02$$
    $$= 1.92 atm$$
  • Question 3
    1 / -0
    A barometer tube 90 cm long contains some air above mercury. The reading is 74.8 cm when true atmospheric pressure is 76 cm and temperature is 30$$^o$$ C. If the reading is observed to be 75.4 cm on a day when temperature is 10$$^o$$C, then find the true pressure.
    Solution
    Let A be the area of the cross-section
    $$V_1 = (90 - 74.8) A = 15. 2 A  cm^3$$
    $$P_1 = 76 - 74.8 = 1.2$$ cm of Hg
    $$P_2 = (P - 75.4)$$ cm of Hg
    $$V_2 = (90 - 75.4) A = 14.6 A  cm^3$$
    $$\displaystyle \frac{P_1V_1}{T_1} = \frac{P_2 V_2}{T_2} = \frac{1.2 \times 15.2 \times 283}{303 \times 14.6} = 75.4 + 1.17$$
    $$= 76.57$$ cm of Hg
  • Question 4
    1 / -0
    Two containers of equal volume contain the same gas at pressures $$P_1$$ and $$P_2$$ and absolute temperatures $$T_1$$ and $$T_2$$, respectively. On joining the vessels, the gas reaches a common pressure $$P$$ and common temperature $$T$$. The ratio $$\displaystyle\frac{P}{T}$$ is equal to
    Solution
    $$P_1V=n_1RT_1$$
    $$P_2V=n_2RT_2$$
    where V is the volume of each vessel.
    When the vessels are joined, $$P(2V)=(n_1 + n_2)RT$$
    $$ \therefore \dfrac{P}{T}= \dfrac{1}{2}\dfrac{(n_1 + n_2)R}{V}=\dfrac{1}{2}(\dfrac{P_1}{T_1} + \dfrac{P_2}{T_2})=\dfrac{P_1}{2T_1} + \dfrac{P_2}{2T_2}$$
  • Question 5
    1 / -0
    One mole of an ideal gas undergoes a process $$P = \displaystyle \frac{P_o}{1 + \left ( \displaystyle\frac{V}{V_o} \right )^2}$$, where $$P_o$$ and $$V_o$$ are constants. Find the temperature of the gas when $$V = V_o$$.
    Solution
    Since the gas is ideal, therefore $$P_o V_o = RT$$

    Using the relation given when $$V = V_o$$ 

    $$P = \displaystyle \frac{P_o}{2}$$

    Thus we get

    $$ \displaystyle \frac{P_o}{2} (V_o) = RT$$

    $$T = \displaystyle \frac{P_oV_o}{2R}$$.
  • Question 6
    1 / -0
    The African bombardier beetle stenaptinus insignis can emit a jet of defensive spray from the movable tip of its abdomen. The beetle's body has reservoirs of two different chemicals. When the beetle is disturbed, these chemicals are combined in a reaction chamber producing a compounds that is warmed from $$20^o$$C to $$100^o$$C by the heat of reaction. The high pressure produced allows the compound to the sprayed out at speeds 19 ms$$^{-1}$$ scaring away predators of all kinds. Assume specific heat of two chemicals and the spray to be same as that of water $$[4.19 \times 10^3 J (kgK)^{-1}]$$ and initial temperature of chemicals to be $$20^o$$C. How many times does the pressure increase?
    Solution
    $$\displaystyle \frac{P_1}{T_1} = \frac{P_2}{T_2}$$
    or $$\displaystyle \frac{P_2}{P_1} = \frac{T_2}{T_1} = \frac{373}{293} = 1.28$$
  • Question 7
    1 / -0
    The correct graph between PV and P of one mol of gas at constant temperature will be
    Solution
    For an ideal gas $$PV=nRT$$
    Thus for a constant temperature, $$PV=constant$$
    Thus $$PV$$ does not change even when P changes.
  • Question 8
    1 / -0
    A gas is filled in a container at any temperature and at pressure 76 cm of Hg. If at the same temperature the mass of gas is increased by 50% then the resultant pressure will be
    Solution
    $$PV=nRT$$
    $$PV=\dfrac{m}{M}RT$$
      $$P=\dfrac{m}{M}\dfrac{RT}{V}$$ also given that P=76cm of Hg
    Given that mass of the gas is increased by 50%
    Now $$P_{1}=\left(\dfrac{m+\dfrac{m}{2}}{M}\right)\dfrac{RT}{V}$$
    $$=\dfrac{3}{2}\dfrac{m}{M}\dfrac{RT}{V}$$
    $$=\dfrac{3}{2}P$$
    =$$\dfrac{3}{2}\times76$$
    =$$114cm\ of\ Hg$$

  • Question 9
    1 / -0
    In the gas equation $$PV= RT$$, V is the volume of
    Solution
    For an Ideal Gas, $$PV=nRT$$
    Here $$V$$ is the volume of n moles of gas.
    Thus for $$PV=(1)RT$$, $$V$$ is the volume of 1 mol of gas.
  • Question 10
    1 / -0
    An enclosure of volume 3 litre contains 16g of oxygen, 7g of nitrogen and 11g of carbondioxide at 27$$^o$$C. The pressure exerted by the mixture is approximately
    Solution
    Total number of moles = number of moles of oxygen + number of moles of nitrogen + number of moles of carbon-di-oxide
    $$\dfrac { 16 }{ 32 } +\dfrac { 7 }{ 14 } +\dfrac { 11 }{ 44 } =1mole$$
    Molecular weight of Carbon-di-oxide = 44g
    Molecular weight of Oxygen =32g
    Molecular weight of  nitrogen=14g
    Using ideal gas equation,
    $$P=\dfrac { nRT }{ V } =\dfrac { 1 \times8.3 \times300 }{ (3\times{ 10 }^{ -3 }) } =8.3atm(nearly)$$
    Hence, Option B is correct.

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