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Solid State Test - 18

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Solid State Test - 18
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  • Question 1
    1 / -0
    Diamond shows ___________ lusture.
    Solution
    Lustre or luster is the way light interacts with the surface of a crystal, rock, or mineral. Adamantine minerals possess a superlative lustre, which is most notably seen in diamond. Such minerals are transparent or translucent, and have a high refractive index (of 1.9 or more). Minerals with a true adamantine lustre are uncommon.
  • Question 2
    1 / -0
    Which of the following compounds would be a white, crystalline solid?
    Solution
    Option $$E$$ is the correct answer.
    Magnesium Oxide is an ionic compound, formed by the transfer of electrons from one element to the other. Since it is an ionic compound, $$MgO$$ is solid. It is also white and crystalline in nature.
  • Question 3
    1 / -0
    The space lattice of diamond is:
    Solution


    The diamond lattice consists of a face-centred cubic Bravais point lattice which contains two identical atoms per lattice point. 

    The distance between the two atoms equals one-quarter of the body diagonal of the cube. The diamond lattice represents the crystal structure of diamond, germanium and silicon. 

    The diamond lattice contains also 4 lattice point per unit cell but contains 8 atoms per unit cell tetrahedrally bonded atoms in each primitive cell.

  • Question 4
    1 / -0
    Identify the system of crystal structure, if a = b $$\neq$$ c and $$\alpha = \beta = 90^{\circ}$$ and $$\gamma = 120^{\circ}$$
    Solution

    In the hexagonal system, there is an axes with six-fold rotation symmetry. Just as in the trigonal system, if we chose this axis to be along the c direction, then we have $$a = b ≠ c$$,$$\ α=β=90^∘$$, $$γ=120^∘$$. There is only one lattice in the hexagonal system.

    Hence, the correct option is $$C$$

  • Question 5
    1 / -0
    The edge length of the NaCl unit cell is if radius of $$Na^+$$ is 97 pm and radius of it is 181 pm :
    Solution
    for NaCl type structure 
    $$2(r_-+r_+)=a$$
    $$2(97+181) = a$$
    $$\therefore a=2\times 278pm$$
    $$\therefore a=556pm$$
    a is edge length
  • Question 6
    1 / -0
    Solids with regular pattern are called______and irregular pattern are called_______.
    Solution
    In crystalline solids, the atoms, ions or molecules are arranged in an ordered and symmetrical pattern that is repeated over the entire crystal. However, no such symmetry or pattern is observed in amorphous solid.
  • Question 7
    1 / -0
    Total number of layer between a distance of $$14R \sqrt { \frac { 2 }{ 3 }  } $$ in help unit cell ?
    Solution

    (Refer to Image)
    In a distance of $$h=4r \sqrt {\cfrac {2}{3}}$$, there are $$3$$ layers.
    Hence in a distance of $$h=14r\sqrt {\cfrac {2}{3}}$$, there will be approximately $$10$$ layers.

  • Question 8
    1 / -0
    Empty space in ccp lattice is
    Solution
    In ccp lattice $$74$$% of the space is occupied by spheres and $$26$$% is empty.
  • Question 9
    1 / -0
    Packing fraction in a body-centred cubic cell of crystals is  
    Solution

  • Question 10
    1 / -0

    Lattice energy is defined as the energy released when 1 mol of an ionic solid is formed from its ions in the gaseous phase. From the following given compounds, the lattice energy is maximum for (compare the only magnitude)

    Solution

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