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Solid State Tes...

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  • Question 1
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    Packing fraction of a unit cell is defined as the fraction of the total volume of the unit cell occupied by the atom(s).$$\displaystyle \text{Packing fraction (P.F)} = \dfrac{\text{Volume of the atom (s) present in a unit cell}}{\text{Volume of unit cell}}$$                                          $$=\dfrac {Z \times \dfrac{4}{3} \pi r^{3}}{a^{3}}$$ Percentage of empty space $$=100-\text{P.F}\times 100$$ where $$Z$$  is the effective number of atoms in a cube, $$r$$ is the radius of an atom and $$a$$ is the edge length of the cube.

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    Percentage of empty space in body centered cubic unit cell is nearly:

  • Question 2
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    If $$a$$ is the edge length, first three nearest neighbour distances for primitive cubic lattice are, respectively:

  • Question 3
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    The density of a pure substance A whose atoms are in cubic closed packed arrangement is $$1$$ g/cc. If all the tetrahedral voids are occupied by B atoms, what is the density (in g cm$$^{-3}$$) of resulting solid?[Atomic mass of $$A=30$$ g/mol and atomic mass of $$B=50$$ g/mol]

  • Question 4
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    Select the correct statement(s) :

  • Question 5
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    Graphite has hcp arrangement of carbon atoms and the parallel planes are $$3.35$$ $$\mathring A$$ apart. The density (in g cm$$^{-3}$$) of graphite is :

  • Question 6
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    The density for an FCC lattice is: 


    [A = atomic wt, N = Avogadro's number, a = lattice parameter]

  • Question 7
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    Which of the following is not an amorphous substance?

  • Question 8
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    If $$A$$ is the atomic mass number of an element, $$N$$ is the Avogadro number and $$a$$ is the lattice parameter, then the density of the element, if it has bcc crystal structure, is_________.

  • Question 9
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    Correct order for lattice energy of the given crystals is :

  • Question 10
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    Lattice energy of NaCl is $$-186$$ kcal/mol. If solution enthalpies of Na$$+$$ and Cl$$^-$$ are $$-97$$ kcal/mol and $$-85$$ kcal/mol respectively. The enthalpy NaCl solution in kcal will be:

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