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Solid State Test - 33

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Solid State Test - 33
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  • Question 1
    1 / -0
    Which crystal system does the unit cell dimensions, $$a\neq b\neq c$$ and $$\alpha= \beta= \gamma$$ represent?
    Solution


    $$a \neq b \neq c $$

    $$\alpha=\beta=\gamma=90^{\circ}$$


    3 types:-

    1. Body centred orthorhombic: lattice point in middle of unit cell.

    2. Base centerd: lattice point in middle of each of 2 ends.

    3. Face centred = middle of each side.

  • Question 2
    1 / -0
    Sodium chloride crystal has a ________ shape.
    Solution
    In $$NaCl$$ crystal, there exists strong ionic bonding between $$Na^{+}$$ and $$Cl^{-}$$ ions. Because of stronger forces of attraction between $$Na^{+}$$ and $$Cl^{-}$$, they remain fixed at their positions, thus, arranging in a definite pattern to give a definite shape.
  • Question 3
    1 / -0
    Pick out the crystalline substance from the following.
    Solution
    In sugar, the constituent particles are arranged in a  specific manner. Hence, it is a crystalline solid.

    In coal, wax, and clay the constituent particles are arranged in a random manner. Hence, it is an amorphous solid.

    Hence, the correct option is $$\text{D}$$
  • Question 4
    1 / -0

    Which of the following is an amorphous substance?

    Solution
    In clay, the constituent particles are arranged in a  random manner. Hence, it is a amorphous solid.
    In zinc, salt and sugar the constituent particles are arranged in a  specific manner. Hence, it is a crystalline solid.
  • Question 5
    1 / -0
    The space lattice of graphite is:
    Solution
    The structure of graphite consists of many flat layers of hexagons. The layers are called graphene sheets. Each carbon atom in the layer is joined by strong covalent bonds to only three other carbon atoms. Compare this with the structure of diamond. Each graphene sheet is itself a giant molecule.
  • Question 6
    1 / -0
    Identify the crystalline solid among the following :
    Solution
    Th e solid which have fixed composition and three dimensional structure is called as crystalline solid. Silver is a crystalline solid because it have fixed composition and structure .
  • Question 7
    1 / -0
    Suppose the mass of a single $$Ag-$$atom is $$m$$. $$Ag$$ metal crystallizes in fcc lattice with unit cell of length $$a$$. The density of $$Ag$$ metal in terms of $$a$$ and $$m$$ is: 
    Solution
    Edge length of the unit cell is $$a$$
    Volume of the unit cell is $$\displaystyle a^3$$
    One fcc unit cell contains $$4 Ag$$ atoms.
    Mass of one $$Ag$$ atom is $$m$$.
    Mass of $$4 Ag$$ atoms is $$4m$$.
    Density $$\displaystyle = \dfrac {mass}{volume} = \dfrac {4m}{a^3} $$
  • Question 8
    1 / -0
    The third layer in Figure - B:

    Solution
    This is an example of a ABAB type packing or the hexagonal closed packing wherein the second row is placed above the first row in such a manner that it fits in the depressions of the first row(tetrahedral voids) and similariy the third layers lie on the tetrahedral voids of the second
  • Question 9
    1 / -0
    Which metal among the following has the highest packing efficiency?
    Solution
    The packing efficiency is is the fraction of volume in a crystal structure that is occupied by constituent particles (volume of space occupied by the spheres/total volume). The majority of metals take on either the hcp or bcc structure. Among the given metals $$Al$$ occupies hexagonal close-packed (hcp) is having 0.74 packing efficiency and other metals form body-centered cubic (bcc) which has  0.68 packing efficiency. 
  • Question 10
    1 / -0
    Which among the following solids crystallises as a face centred cube?
    Solution
    S.No.ElementType of packing
     AFe  bcc
     BRb bcc
     C U bcc
     D Pt fcc
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