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Aldehydes Ketones and Carboxylic Acids Test - 24

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Aldehydes Ketones and Carboxylic Acids Test - 24
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  • Question 1
    1 / -0
    Carbonyl group of aldehyde and ketone contain ________ groups.
    Solution
    Aldehyde and ketone formula are $$R-CHO$$, $$R-(C=O)-R$$
    Thus, they contain carbon and oxygen in their groups.
  • Question 2
    1 / -0
    Which of the following IUPAC name will be used to name carboxylic acid functional group?
    Solution
    The following IUPAC name will be used to name carboxylic acid functional group is -oic acid.
    Hence option B is correct.
  • Question 3
    1 / -0
    The carboxylic acid includes the functional group:
    Solution
    The carboxylic acid includes the functional group carboxyl and hydroxyl group
    Hence option C is correct.
  • Question 4
    1 / -0
    Acetyl chloride cannot be obtained by treating acetic acid with:
    Solution
    $$CH_3COOH \xrightarrow {PCl_3} CH_3COCl +POCl +HCl$$

    $$CH_3COOH \xrightarrow {PCl_5} CH_3COCl +HCl+POCl_3$$

    $$CH_3COOH \xrightarrow {SOCl_2} CH_3COCl +SO_2 +HCl$$

    With chloroform acetyl chloride cannot be formed with acetic acid.
  • Question 5
    1 / -0
    Which of the following compounds are not soluble in water?
    Solution
    Formaldehyde, acetaldehyde and acetone all are water soluble. These are polar molecules and dissolve in polar solvent. Water is a polar solvent.
  • Question 6
    1 / -0
    IUPAC name of $$HOOCCH_2C(OH)(COOH)CH_2COOH$$ is
    Solution
    Correct IUPAC name of given compound is 2-Hydroxy-1,2,3-propanetri-carboxylicacid. Citric acid is its common name.
  • Question 7
    1 / -0
    What is the IUPAC name of $$CH_3CH=CH-COOH$$?
    Solution
    $$\overset{4}{C}H_3 \overset{3}{C}H= \,^{2}CH- \,^{1}COOH$$
    $$ But-2-ene-1-oic \, acid$$
  • Question 8
    1 / -0
    What is the common name of $$CH_2=CHCOOH$$?
    Solution
    Common name of $$CH_2=CHCOOH$$ is acrylic acid.
  • Question 9
    1 / -0
    The compound $$X$$ on oxidation gives a mixture of acetic acid and formic acid, while $$Y$$ on oxidation forms only propionic acid. $$X$$ and $$Y$$ are :
    Solution
    The compound $$X$$ on oxidation gives a mixture of acetic acid and formic acid, while $$Y$$ on oxidation forms only propionic acid. $$X$$ and $$Y$$ are $$\displaystyle CH_3  - CO - CH_3$$ and $$\displaystyle CH_3 - CH_2 - CHO$$ respectively.

    $$\displaystyle CH_3  - CO - CH_3 \xrightarrow {\text {oxidation}} CH_3-COOH + H-COOH$$
    $$\displaystyle CH_3 - CH_2 - CHO \xrightarrow {\text {oxidation}} CH_3-CH_2-COOH $$

    Option C is correct
  • Question 10
    1 / -0
    As the carbon chain increases in aldehyde and ketone compounds, solubility in water:
    Solution
    As the carbon chain increases in aldehyde and ketone compounds, solubility in water decreases.
    Thus, aldehydes and ketones with few carbon atoms are water soluble whereas the one having several $$C$$ atoms are water insoluble. With increase in the number of $$C$$ atoms, the hydrophobic part of molecule increases. Hence, water solubility decreases.
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