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  • Question 1
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    The vapour pressure of two pure liquids $$A$$ and $$B$$ which form an ideal solution are $$500$$ and $$800$$ torr respectively at $$300K$$. A liquid solution of $$A$$ and $$B$$ for which the mole fraction of $$A$$ is $$0.60$$ is contained in a cylinder closed by a piston on which the pressure can be varied. The solution is slowly vaporized at $$300K$$ by decreasing the applied pressure.

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    The composition of vapour when first bubble formed is:

  • Question 2
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    A liquid A and B form an ideal solution. If vapour pressure of pure A and B are $$500N{ m }^{ -2 }$$ and $$200N{ m }^{ -2 }$$ respectively, the vapour pressure of a solution of A and B containing 0.2 mole fraction of A would be:

  • Question 3
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    A mixture of ethyl alcohol and propyl alcohol has a vapour pressure of $$290\ mm$$ at $$300\ K$$. The vapour pressure of propyl alcohol is $$200\ mm$$. If the mole fraction of ethyl alcohol is $$0.6$$, its vapour pressure (in $$mm$$) at the same temperature will be:

  • Question 4
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    A $$3.00\ L$$ oxygen gas is collected over water at $${27}^{o}C$$ when the barometric pressure is $$787\ Torr$$. If vapour pressure of water is $$27\ Torr$$ at $${27}^{o}C$$, moles of $$O_{2}$$ gas will be?

  • Question 5
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    The vapour pressure of pure water is 760 mm at $$25^{ 0 }C$$.The vapour pressure of solution containing 1(m) solution of glucose will be:

  • Question 6
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    Which of the following is least soluble?

  • Question 7
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    Which of the following condition is not followed for an ideal solution?

  • Question 8
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    Which of the following pair will form an ideal solution?

  • Question 9
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    $$3$$ moles of $$P$$ and $$2$$ moles of $$Q$$ are mixed, what will be their total vapour pressure in the solution if their partial vapour pressures are $$80$$ and $$60$$ respectively?

  • Question 10
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    How many grams of sucrose must be added to $$320g$$ of water to lower the vapour pressure by $$1.5mm$$ $$Hg$$ at $${25}^{o}C$$?
    (Given: The vapour pressure of water at $${25}^{o}C$$ is $$23.8mm$$ $$Hg$$ and molar mass of sucrose is $$324.3g/mol$$)

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