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  • Question 1
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    Liquids A and B forms an ideal solution . At TK , $$ P^0_A = 0.4\, bar $$ and $$ P^0_B = 0.6\, bar $$. In a cylinder piston arrangement, 2.0 moles of vapours of liquid A and 3.0 moles of vapours of liquid B are taken at TK and 0.3 bar

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    Which of the following is the only incorrect informarion regarding the composition of the system at 0.51 bar pressure ?

  • Question 2
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    Directions For Questions

    Liquids A and B forms an ideal solution . At TK , $$ P^0_A = 0.4\, bar $$ and $$ P^0_B = 0.6\, bar $$. In a cylinder piston arrangement, 2.0 moles of vapours of liquid A and 3.0 moles of vapours of liquid B are taken at TK and 0.3 bar

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    If the vapour are compressed slowly and isothermally , at what pressure , the first drop of liquid will appear ?

  • Question 3
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    One having high vapour pressure at temperature below its melting point is?

  • Question 4
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    $$2.0\ g$$ mixture of sodium carbonate and sodium bicarbonate on heating to constant weight gave $$224\ mL$$ of $$CO_{2}$$ at N.T.P.
    The $$\%$$ weight of sodium bicarbonate in the mixture is:

  • Question 5
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    The compound $$Na_2 CO_3 . x H_2O$$ has $$50  \%  H_2O$$ by mass. The value of "x" is :

  • Question 6
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    Directions For Questions

    Liquid A ( molar mass = 100 g/mol and density = 1.25 g/ml ) and B ( molar mass = 50 g/mol and density = 1.0 g/ml) form an ideal solution . the molal volume of liquid A increases by afactor of 3800 as it vaporizes at $$ 27^0 $$C and that of liquid B increases by factor of 7600 at $$ 27^0 C $$ A solution of liquid A and B at $$ 27^0 C $$ has a vapour pressure of 54.0 (n R -= 0.08 atm/K-mol ) 

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    The vapour pressure of pure liquid A at $$ 27^0 C $$ is

  • Question 7
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    Directions For Questions

    The lowering vapour pressure on adding non volatile solute in a pure liquid solvent may be measured by ostwald walker method. in this method dry air is first passed through a series of vessels having the solution, then through a series of vessels having pure solvent and finally through a vessel ( normally U Tube) having the absorbent of the solvent.the masses of the solution and pure solvent decreases due to removal of vapour of solvent in the flow of air and the m,ass of absorbent increases due to absorption of the vapour of solvent , in order to make the air, dery . by measuring the changes in mass we may determine the lowering of vapour pressure and hence, the composition of solution using raoults law.

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    If the experimenty is performed aqueous $$ AlCl_3 $$ solution (a= 0.8 ) prepared by dissolving 1 mole of $$ AlCl_3 $$ in 17 mole of water and the decrease in the mass of solution in the experiment is found to be 0.18 g then the increase in the mass of absorbent should be

  • Question 8
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    At $$80^o C$$, the vapour pressure of pure liquid A is 520 mm Hg and that of pure liquid B is 1000 mm Hg. If a mixture solution of A and B boils at $$80^o C$$and 1 atm pressure, the amount of A in the mixture is :

    (1 atm=760 mm Hg)

  • Question 9
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    Sugar in urine sample can be detected by:

  • Question 10
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    $$50 mL$$ of solution of $$ Na_2CO_3 $$ neutralizes $$49.35 mL$$ of $$4 N \ HCl$$ . the reaction is represented as 
    $$ CO^{2-}_3 +2H^+ \rightarrow CO_2 +H_2O $$
    The density of this $$ Na_2CO_3 $$ solution is 1.25 g $$ mL^{-1} ,$$ the percentage of $$  Na_2CO_3$$ in it is :

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