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Electrochemistry Test - 28

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Electrochemistry Test - 28
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  • Question 1
    1 / -0
    The presence of electrolytes ................ the rate of corrosion. 
    Solution
    The presence of electrolyte increase the concentration of electron and thus increasing the mobility of electron due to which rate of corrosion increases.
  • Question 2
    1 / -0
    20 mL of KOH solution was titrated with 0.20 M $$H_2SO_4$$ solution in a conductivity cell. The data obtained were plotted to give the graph shown below.
    The concentration of the KOH solution was :

    Solution
    From the graph given, the equivalent point is reached at 15mL of H₂SO₄.
    Milli-equivalents of an acid or base = n-factor x Molarity x volume (in mL)
    n-factor for H₂SO₄ = 2 and for KOH = 1

    We know that, at equivalent point,
    m.eq. of acid = m.eq. of base
    ⇒ 2 x 0.20 x 15 = 1 x M x 20
    ⇒ M = 0.3 mol/L

    Hence, option A is correct.
  • Question 3
    1 / -0
    _____ refers to amount of electricity while _____ refers to rate at which it flows.
    Solution
    Coulomb refers to amount of electricity while ampere refers to rate at which it flows.  Coulomb is the quantity of lctricity passed through a conductor/ electrolyte when a current of 1A strength flows for 1 second. In other words, coulomb $$=$$ amperes $$\times$$ second.
  • Question 4
    1 / -0

    How many coulombs are required for the oxidation of 1 mol of $$H_2O \ to \ O_2$$?

    Solution

    $$H_{2}O\, \rightarrow\, 2H^{\oplus}\, +\, 2e^-\, +\, \displaystyle \frac{1}{2}\, O_2$$

    $$2\, F\, \equiv\, 1\, mol\, of\, H_2O\, =\, \displaystyle \frac{1}{2}\, mol\, of\, O_2$$

    $$\therefore\, 2\, \times\, 96500\, C\, =\, 1.93\, \times\, 10^5\, C$$

    Hence, option B is correct.

  • Question 5
    1 / -0
    In an electrolytic cell current flows:
    Solution

  • Question 6
    1 / -0
    When iron is rusted, it is :
    Solution

    Oxidation of iron happens as shown in the image

  • Question 7
    1 / -0
    When the electric current is passed through a cell having an electrolyte, the positive ions move towards cathode and negative ions towards the anode. If the cathode is pulled out of the solution :-
    Solution
    When the electric current is passed through a cell having an electrolyte, the positive ions move towards cathode and negative ions towards the anode. If the cathode is pulled out of the solution,
    the positive and negative ions will start moving randomly not under the influence of the electrical field by due to movement of electrolyte.
  • Question 8
    1 / -0
    Corrosion of metals can be prevented when contact between metal and ________ is cut off.
    Solution
    Corrosion is basically oxidation of metal in presence of oxygen. So it can be prevented by cutting off $${ O }_{ 2 }$$
  • Question 9
    1 / -0
    In an electrochemical cell that function as a voltaic cell:
    Solution
    Reduction always occurs at cathode
    Oxidation always occurs in anode
    These two process occurs in same way independent of nature of cell whether voltaic or electrolytic.
  • Question 10
    1 / -0
    Corrosion of metals can be prevented when contact between metal and .......... is cut off.
    Solution
    Corrosion of the metal can be prevented if the contact between metal and air is cut off.

    Thus Option c is correct.
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