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Electrochemistr...

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  • Question 1
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    for the cell reaction
    $$Cu^{2+}(C_1aq)+Zn(s)=Zn^{2+}(C_2aq)+Cu(s)$$
    of an electrochemical cell, the change in free energy at a given temperature is a function of 

  • Question 2
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    The main reason for not using a mercury electrolytic cell in NaOH manufacture is that 

  • Question 3
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    In which cell the free energy of a chemical reaction is directly converted into electricity 

  • Question 4
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    $$E^o_{Cell}$$ for some half-cell reactions are given below. On the basis of these mark the correct answers.


    (a) $$H^- (aq) + e^- \rightarrow \frac{1}{2} H_2 (g); E^o_{Cell} = 1.23V$$

    (b) $$2H_2O(l) \rightarrow O_2(g) + 4H^- (aq) + 4e^- ; E^o_{Cell} = 1.23V$$

    (c) $$2SO^{2-}_4(aq) \rightarrow S_2O^{2-}_8(aq) + 2e^-; E^o_{Cell} = 1.96V$$

  • Question 5
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    $$E_n = -\dfrac{313.6}{n^2}$$, if the value of $$E_i = -38.84$$ to which value 'n' corresponds?

  • Question 6
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    Two electrolytic cells containing $$CuSO_{4}$$ and $$AgNO_{4}$$ respectively are connected in series and a current is passed through them unit 1 mg of copper is deposited in the first cell. The amount of silver deposited in the second cell during this time is approximately 
    [ Atomic weight of copper and silver are respectively 63.57 and 107.88] 

  • Question 7
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    Resistance of a voltameter is 2$$\Omega $$, it is connected in series to a battery of 10 V through a resistance of 3$$\Omega $$ . In a certain time mass deposited on cathode is 1 gm. Now the voltameter and the 3$$\Omega $$resistance are connected in parallel with the battery. Increase in the deposited mass on cathode in the same time will be

  • Question 8
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    If redox reaction takes place in cell then electromotive force (e.m.f) of cell will be:

  • Question 9
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    Which of the following mixtures represents rusting of iron?

  • Question 10
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    The amount of charge required to liberate 9 gm of aluminium ( atomic weight = 27 and valency = 3 ) in the process of electrolysis is ( Faraday's number = 96500 coulombs/gm equivalent)

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