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Electrochemistry Test - 9

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Electrochemistry Test - 9
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  • Question 1
    1 / -0

    Hydrogen gas is not liberated when the following metal is added to dil. HCl.

    Solution

    Ag is less reactive than Hydrogen.

  • Question 2
    1 / -0

    The hydrogen electrode is dipped in a solution of pH 3 at 25°C. The potential would be (the value of 2.303 RT/F is 0.059 V)

    Solution

    2H+ + 2e- = H2
    Ecell = -0.0591 log(PH2/[H +]2)

  • Question 3
    1 / -0

    The one which decreases with dilution is

    Solution

    Specific conductance decreases with dilution as number of ions decreases per unit volume.

  • Question 4
    1 / -0

    The standard electrode potential for the half cell reactions are

    Zn++ + 2e− → Zn, E0 = -0.76V

    Fe++ + 2e− → Fe, E0 = -0.44V

    The e.m.f. of the cell reaction Fe++ + Zn → Zn++ + Fe is

    Solution

    E0 cell = E0cathode - E0anode

    = -0.44 - (-0.76) = +0.32V

  • Question 5
    1 / -0

    Given

    1. Cu2+ + 2e- →→ Cu, E0 = 0.337 V
    2. Cu2+ + e- →→ Cu+, E0 = 0.153 V
      Electrode potential E° for the reaction Cu2+ + e- → Cu will be
    Solution

    Eocell = 2(0.337)-0.153

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