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Chemical Kineti...

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  • Question 1
    1 / -0

    In the decomposition of oxalic acid following data were obtained.

    Time (second)
    0
    300
    600
    Volume of $$KMnO_4$$ used in mL
    22.0
    17.0
    13.4
    If reaction obeys 1st order kinetics then determine the rate constant K and half-life period:

  • Question 2
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    For a reaction for which the activation energies of forward and reverse reactions are equal:

  • Question 3
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    The rate constant for an isomerisation reaction, $$A\rightarrow B$$ is $$4.5\times 10^{-3} min ^{-1}$$. If the initial concentration of A is 1 M,  the rate of the reaction after 1 hr will be: 

  • Question 4
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    The activation energy for a chemical reaction depends upon:

  • Question 5
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    $$A\rightarrow B+2C$$

    At $$100^oC$$, in above gaseous reaction, is observed to be of the first order. On starting with pure A, at the end of $$14$$ minutes, the total pressure found to be $$264$$ mm of Hg. After a long time, the total pressure of the system was $$450$$ mm of Hg. 
    Rate constant of the reaction is:

  • Question 6
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    At room temperature, the reaction between $$NO$$ and $$O_2$$ to give $$NO_2$$ is fast, while that between $$CO$$ and $$O_2$$ is slow. It is due to:

  • Question 7
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    For a first-order reaction, $$A\rightarrow Product$$, the initial concentration of A is 0.1M and after 40 minutes it becomes 0.025 M. Calculate the rate of reaction at reactant concentration of 0.01 M:

  • Question 8
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    The maximum value of activation energy is equal to:

  • Question 9
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    In a first order reaction the concentration of reactant decreases from 800 $$mol/dm^3$$ to $$50\ mol/dm^3$$ in $$2\times 10^4 sec$$. The rate constant of reaction in $$sec^{-1}$$ is:

  • Question 10
    1 / -0

    Which of the following is not correct reason for the substantially lower rate of reaction than the collision frequency?

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