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Chemical Kineti...

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  • Question 1
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    Directions For Questions

    The rate law expresses the relationship between the rate of a reaction and the rate constant and the concentrations of the reactants raised to some powers. For the general reaction:
    $$aA+bB   \rightarrow  cC + dD$$
    Rate law takes the form
    $$r = k [A]^x [B]^y$$
    where $$x$$ and $$y$$ are numbers that must be determined experimentally, $$k$$ is the rate constant and $$[A]$$ and $$[B]$$ are a concentration of $$A$$ and $$B$$ respectively.

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    The initial rate of zero-order reaction of the gaseous equation $$A$$ (g) $$\rightarrow$$ $$2B$$ (g) is 10$$^{-2}$$ M min$$^{-1}$$ if the initial concentration of $$A$$ is 0.1 M. What would be a concentration of $$B$$ after $$60$$ seconds?

  • Question 2
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    A certain substance A is mixed with an equimolar quantity of substance B. At the end of an hour, A is 75% reacted. Calculate the time when A is 10% unreacted. (Given: order of reaction is zero)

  • Question 3
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       Time t $$\infty $$
     Rotation of Glucose & Fructose  $$ r_{t}  $$ $$r _{\infty }$$ 
    $$S\rightarrow$$ $$G+F  $$ 
    What id the value of $$k$$ for the above reaction under given circumstances?

  • Question 4
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    A metal slowly forms an oxide film which completely protects the metal when the film thickness is 3.956 thousandths of an inch. If the film thickness is 1.281 thou. in 6 weeks, then the time it will take before it is 2.481 thou. is :(the rate of film formation follows first-order kinetics)

  • Question 5
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    At $$100^{\circ}$$C the gaseous reaction $$A\rightarrow $$2B+C was observed to be of first order. On starting with pure A it is found that at the end of 10 minutes the total pressure of system is 176mm.Hg and after a long time 270mm Hg.
    Initial pressure of A is:

  • Question 6
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    The rate constant for disappearance of reactant as mentioned in is $$\displaystyle 2 \times 10^{-2} mol L^{-1} sec^{-1}$$, if the concentration of the reactant after 25 sec is 0.25M, the initial concentration is:

  • Question 7
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    For a reversible first - order reaction $$A\rightleftharpoons B K_{1}=10^{-2}s^{-1}$$ and $$[B]_{eq}=4$$. If $$[A]_{0}=0.01$$ mole $$L^{-1} $$ and $$ [B]_{0}=0$$, what will be the concentration of B after 30 s?

  • Question 8
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    In this case, we have (Consider it as a first-order reaction)
                        $$A\rightarrow B+C$$
    Time                  $$t$$                 $$\infty $$
    Total pressure  $$ p_{2}$$          $$             \ \ \:\:\:\:p_{3}$$
    Then $$k$$ is:

  • Question 9
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    $$\displaystyle SO _{2}Cl _{2}(g)\rightarrow SO_{2}(g)$$ 


    The given reaction is a first order gas reaction with $$k=2.2 \times \displaystyle 10^{-5}sec^{-1}$$ at $$ 320^{\circ}$$C. What % of $$SO_{2}Cl_{2}$$ is decomposed on heating this gas for 90 min?

  • Question 10
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    A vessel contains dimethy 1 ether at a pressure of 0.4 atm. Dimethyl ether decomposes as $$ CH_{3}OCH_{3}(g)\rightarrow CH_{4}(g)+CO(g)+H_{2}(g).$$ The rate constant of decomposition is $$4.78\times10^{-3}min.$$ The ratio of initial rate of diffusion after 4.5 hours of initiation of decomposition is:

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