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Chemical Kineti...

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  • Question 1
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    What is the formula to find the value of $$t_{1/2}$$ for a zero order reaction?

  • Question 2
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    In the presence of an acid, the initial concentration of cane sugar was reduced from $$ 0.20 $$ to $$ 0.10 $$ molar in $$ 5 $$ hours and from $$0.2 $$ to $$ 0.05 $$ molar in $$10 $$ hours. The reaction is of:

  • Question 3
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    Directions For Questions

    Population growth of humans and bacteria follow first-order growth kinetics. Suppose, $$100$$ bacteria are placed in a flask containing nutrients for the bacteria so that they can multiply. A study at $${ 35 }^{ \circ}C$$ gave the following results:

    $$\begin{matrix} Time\left( minutes \right)  & 0 & 15 & 30 & 45 & 60 \\ Number\ of\ bacteria & 100 & 200 & 400 & 800 & 1600 \end{matrix}$$

    ...view full instructions

    The rate constant for the first-order growth of bacteria can be calculated using:

  • Question 4
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    The formation of $$H_2O_2$$ in the upper atmosphere follows the mechanism: $$H_2O+O\rightarrow 2OH \rightarrow H_2O_2$$; $$\Delta H=72\ kJ mol^{-1}$$, $$E_a=77\ kJ$$ $$mol^{-1}$$. 


    Then, $$E_a$$ for the backward reaction will be (per mol):

  • Question 5
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    Match the List-I and List-II:

    List-IList-II 
    (A) Rate constant has the same unit as the rate of reaction.(i) One 
    (B) Reactions having apparent molecularity more than three reaction(ii) Zero order
    (C) Reactions having molecularity two but order of reaction is one.(iii) Complex reaction
     (D) For a reaction, $$A \rightarrow B$$, the rate of reaction doubles as the ocular reaction concentration of A is doubled. (iv) Pseudo unimolecular reaction

  • Question 6
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    At room temperature, the reaction between $$NO$$ and $$O_2$$ to give $$NO_2$$ is fast while that of between $$CO$$ and $$O_2$$ is slow. It is because:

  • Question 7
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    A certain reaction rate increases $$1000$$ folds in the presence of a cataylst at $$27^{\circ}C$$. The activation energy of the original pathway is $$98\ kJ/mol$$. What is the activation energy of the new pathway?

  • Question 8
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    A first-order reaction is $$40$$% complete after $$8$$ min. How long will it take before it is $$90$$% complete? 

  • Question 9
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    Which among the following is wrong for $$1^{st}$$ order reaction?

  • Question 10
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    Which of the following are the correct representations of a zero order reaction, where A represents the reactant?

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