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Chemical Kineti...

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  • Question 1
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    The following Rice-Herzfeld mechanism has been suggested for the formation of phosgene $$CO{Cl}_{2}$$:
    (1) $${ Cl }_{ 2 }\longrightarrow 2Cl\quad \left[ { K }_{ 1 }={ A }_{ 1 }.{ e }^{ -{ E }_{ { a }_{ 1 } }/RT } \right] $$
    2. $$2Cl\longrightarrow { Cl }_{ 2 }\quad \left[ { K }_{ 2 }={ A }_{ 2 }.{ e }^{ -{ E }_{ { a }_{ 2 } }/RT } \right] $$
    3. $$Cl+CO\longrightarrow COCl\quad \left[ { K }_{ 3 }={ A }_{ 3 }.{ e }^{ -{ E }_{ { a }_{ 3 } }/RT } \right] $$
    4. $$COCl\longrightarrow Cl+CO\quad \left[ { K }_{ 4 }={ A }_{ 4 }.{ e }^{ -{ E }_{ { a }_{ 4 } }/RT } \right] $$
    5. $$COCl+{ Cl }_{ 2 }\longrightarrow COCl +Cl\quad \left[ { K }_{ 5 }={ A }_{ 5 }.{ e }^{ -{ E }_{ { a }_{ 5 } }/RT } \right] $$

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    What is overall activation energy of reaction, if steps (1) to (4) are much faster than (5)?

  • Question 2
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    Arrhenius equation gives the change in rate constant (and hence rate of reaction) with temperature. If the activation energy of the reaction is found to be equal to $$RT$$, then

  • Question 3
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    Two reactions: (I) $$A\rightarrow products$$ and (II) $$B\rightarrow products$$, follow first-order kinetics. The rate of reacion-I is doubled when temperature is raised from $$300$$ to $$310K$$. The half-life for this reaction at $$310K$$ is $$30min$$. At the same temperature, $$B$$ decomposes twice as fast as $$A$$. If the energy of activation for the reaction II is half that of reaction I, the rate constant of reaction II at $$300K$$ is

  • Question 4
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    For a zero-order reaction: $$2{ NH }_{ 3 }(g)\rightarrow { N }_{ 2 }(g)+3{ H }_{ 2 }(g)$$, the rate of reaction is $$0.1atm/s$$. Initially only $${ NH }_{ 3 }(g)$$ was present at $$3atm$$ and the reaction is performed at constant volume and temperature. The total pressure of gases after $$10s$$ from the start of reaction will be

  • Question 5
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    Desorption of a gas from metal surface follows first-order kinetics. The rate constant of desorption can be given by Arrhenius equation. If the desorption of hydrogen on manganese is found to increase $$10$$ times on increasing the temperature from $$600$$ to $$1000 K$$, the activation energy of desorption is :

  • Question 6
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    Rate of an uncatalyzed first-order reaction at $$T$$ $$K$$ is half of the rate of a catalyzed reaction at $$0.5T$$ $$T$$. If the catalyst lowers the threshold energy by $$20\ kcal$$, what is the activation energy of the uncatalyzed reaction?
    $$\left( T=300K,\ln { 2 } =0.7 \right) $$

  • Question 7
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    Which of the following curves represents a zero order reaction?

  • Question 8
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    Which of the following curves represents a first order reaction?

  • Question 9
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    The reaction $$A+B\to C+D;\ \Delta H=25\ kJ/ mole$$ should have an activation energy :

  • Question 10
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    The plot of concentration of a reactant vs time for a chemical reaction is shown below :
    The order of this reaction with respect to the reactant is: 

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