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Chemical Kineti...

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  • Question 1
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    If the order of the reaction $$x+y\xrightarrow[]{hv}xy$$ is zero, it means that the rate of ____

  • Question 2
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    Which the following statements is true for a first order reaction?

  • Question 3
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    Fill in the blanks by choosing the correct option:


    Order of the reaction is the $$ \underline {X}  $$ of the powers to which concentration terms are raised in experimentally determined rate equation. The unit of first order rate constant is $$  \underline {Y} $$. The units of first order rate constant when concentration is measured in terms of pressure and time in minute is $$ \underline {Z} $$

  • Question 4
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    Cyclopropane rearranges to form propene
    $$ \Delta \rightarrow CH_3 -CH =CH_2 $$
    this follows first order kinetics. the rate constant is $$ 2.714 \times 10^{-3} sec^{-1} $$the initial concentration of cyclopropane is $$ 0.29 M $$what will be concentration  of cyclopropane after 100 sec ?

  • Question 5
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    the half - life of the reaction $$ X \rightarrow Y $$ following first  order kinetics , when the initial concentration of X is $$ 0.01 mol L^{-1} $$ and initial rate is $$ 0.00352 mol L^{-1} min^{-1} $$ will be 

  • Question 6
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    the rate constant for a first order reaction is $$ 2 \times 10^{-2} min^{-1} $$ the half -life period of reaction is 

  • Question 7
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    Rate constant in case of first order reaction is 

  • Question 8
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    Which of the following is incorrect statement ?

  • Question 9
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    The activation energy of the reaction, $$A + B \rightarrow C + D + 38kcal$$ is $$20$$ kcal, What would be the activation energy of the reaction,
    $$C + D \rightarrow A + B$$

  • Question 10
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    In a certain first-order reaction, $$B^{n+}$$ is getting converted to $$B^{(n+4)+}$$  in solution. The rate constant of this reaction is measured by titrating a volume of the solution with a reducing agent which reacts only with $$B^{n+}$$ and $$B^{(n+4)+}$$. In the process, it converts  to $$B^{n+}$$ to $$B^{(n-2)+}$$ and $$B^{(n+4)+}$$ to $$B^{(n-1)+}$$,At $$t=0$$ the volume of reagent consumed is 55 ml and at $$t = 20$$ min, the volume used is 70.5 ml. The rate constant for the conversion of $$B^{n+}$$ of $$B^{(n+4)+}$$ (ln 2 = 0.7, ln 5 = 1.6) 

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