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Surface Chemistry Test - 26

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Surface Chemistry Test - 26
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  • Question 1
    1 / -0
    Which letter corresponds to the activation energy in this reaction without the addition of a catalyst?

    Solution
    The letter A corresponds to the activation energy in this reaction without the addition of a catalyst. Activation energy is the minimum amount of energy that the reactants must posses to complete the reaction. For uncatalyzed reaction, it is maximum.
  • Question 2
    1 / -0
    What is a sol?
    Solution

    Hint: Sol is a gel-like substance.

    Correct Answer: Option A

    Explanation:

    Sol is a colloidal suspension when a solid is dispersed in a liquid.

    An example of sol is a gel, blood, paint, etc.

    A liquid is dispersed in a gas called aerosols.

    A gas dispersed in liquid or solid called foam.

    Final Answer: Sol is formed when solid is dispersed in the liquid.

  • Question 3
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    The process of enzyme catalysis of biological processes follows a simple pathway and involves three principal species.
    The substrate, which we will represent as S, is the molecule that is to undergo reaction. The enzyme, E, acts as the catalyst, and the product, P, is the result of the reaction.
    The substrate, S, attaches to a receptor site on the enzyme, E, where it is held in place as the reaction proceeds. Once reaction is completer, the product, P, is released from the receptor site, along with any remaining portion of the substrate molecule.
    The process can be represented as shown below, where S-E represents the substrate, bound to the catalyst. As the product forms, the receptor site on the catalyst is again freed to accept another substrate molecule.
    $$S + E \rightarrow [S - E]\rightarrow P + E$$
    The reaction rate can be investigated either in terms of decreasing concentration of substrate, or increasing appearance of product.
    As part of her senior-year STEM project, Athena designs an experiment to study a particular enzyme-catalyzed reaction. Since the product of the reaction is a colored species, she sets up a colorimetric interface to measure the rate of appearance of the colored product, in units of concentration of product over time: $$\dfrac {mol.L^{-1}}{min}$$, or simply, $$\dfrac {M}{min}$$. The plot of product formation vs time appears below.
    By design, Athena's experiment began with a large excess of the substrate, S, relative to the enzyme, E.
    Which of the following offers the BEST description of the results of her study?

  • Question 4
    1 / -0
    Increased with the addition of a catalyst :
    Solution
    A catalyst is a substance which speeds up a reaction but is chemically unchanged at the end of the reaction. When the reaction has finished, you would have exactly the same mass of catalyst as you had at the beginning
  • Question 5
    1 / -0
    Catalyst used in Rosenmund reaction is:
    Solution

    A catalyst used in Rosenmund reaction can be prepared by reduction of $$palladium(II) \space chloride$$ solution in the presence of $$BaSO_4$$

    The Palladium Catalyst used in Rosenmund’s reduction must be poisoned with $$BaSO_4$$ because the untreated catalyst $$Palladium (Pd)$$ is too reactive and will undergo over reduction forming other products.

  • Question 6
    1 / -0
    Which letter corresponds to the total change in energy for the overall reaction?

    Solution
    D is the correct answer.  Since the energy required for the overall reaction is the difference between the energy of the products and the energy of the reactants. Here it is represented by D.
  • Question 7
    1 / -0
    To which of the following category does ice-cream belong?
    Solution

    An emulsion is a colloid of two or more immiscible liquids where one liquid contains a dispersion of the other liquids. In other words, an emulsion is a special type of mixture made by combining two liquids that normally don't mix. 

    • Oil and water mixtures are emulsions when shaken together. The oil will form drops and disperse throughout the water.

    • Ice-cream is an emulsion of fat globules in a sugar-water solution.
  • Question 8
    1 / -0
    The process of separating of cream from milk is called :
    Solution
    The process of separation of two liquids of an emulsion into separate layers is known as demulsification. It can be brought about by heating, centrifuging etc. For example, cream is separated from milk by centrifuging.
  • Question 9
    1 / -0
    Soft soaps are:
    Solution
    Potassium salts of fatty acids, containing no free alkali, are called soft soaps.
  • Question 10
    1 / -0
    Which one of the following systems has the smallest sized domains in its dispersed phase?
    Solution
     The average diameter of droplets in macro-emulsion is close to one millimeter (i.e., 10−3 m). Therefore, since micro- means 10−6
    and emulsion implies that droplets of the dispersed phase have diameters close to 10−3 m,
    the micro-emulsion denotes a system with the size range of the dispersed phase in the
    10−6 × 10−3 m = 10−9 m range.
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