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The p-Block Elements Test - 49

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The p-Block Elements Test - 49
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  • Question 1
    1 / -0
    Equal masses of $$S_2, S_4$$ and $$S_8$$ are taken. Highest number of free species are present in:
    Solution
    The order of molecular weights will be
    $${ S }_{ 2 }<{ S }_{ 4 }<{ S }_{ 8 }$$.
    So, if the the equal masses are taken, then highest number of molecules will be in $${ S }_{ 2 }$$.
    So, correct answer is option A.
  • Question 2
    1 / -0
    The nitride salt of $$Ca$$ when treated with $$H_{2}O$$ gives:
    Solution

    When calcium nitride reacts with di nitrogen it forms ammonia and calcium hydroxide. 

    $$Ca_3N_2 + 6 H_2O\rightarrow 3 Ca(OH)_2 + 2 NH_3$$.

  • Question 3
    1 / -0
    Which property is most important in making fluorine, the strongest oxidising halogen?
    Solution
    $$\displaystyle\frac{1}{2}F_2+e^-+aq. \rightarrow F^-(aq),$$

    $$\Delta

    H=\underset{(+ve)}{H_{Gibbs}}+\underset{Hydrogen

    \ enthalpy}{\underset{(-ve)}{H_{Elec.

    gain}}+\underset{(-ve)}{H_{hyd}}}=-ve$$

    Since the heat of hydration for fluorine is very high and $$-$$ve. (due to small size)

    The overall reaction is highly exothermic and therefore fluorine shows strongest oxidizing nature.

    Hence, option $$A$$ is correct.
  • Question 4
    1 / -0
    Which of the following is not a peroxy acid?
    Solution
    Perchloric acid is not a peroxy acid while other given acids are examples of peroxy acids.

     A peroxy acid is an acid that contains an acidic –OOH group or peroxo linkage (−O−O− linkage).

    Option D is correct.

  • Question 5
    1 / -0
    Helium is used in balloons in place of hydrogen because it is:
    Solution

    Helium is used in balloons in place of hydrogen because it is incombustible. $$He$$  do not catch fire like hydrogen. $$He$$ is a inert element. Hence, option A is correct.

  • Question 6
    1 / -0
    The catalyst used in the manufacture of nitric acid by Ostwald's process is: 
    Solution

  • Question 7
    1 / -0
    An element is oxidised by fluorine and not by chlorine. Identify the element.
    Solution
    $$\begin{array}{l}\text{ Flourine is more Electronegative element than Oxygen and Oxygen is more Electronegative }\\\text{ than Chlorine. }\\\text{ Hence, Flourine can oxidise Oxygen whereas Chlorine reduced Oxygen. }\\\text{ Hence option }(C)\text{ is correct. }\end{array}$$
  • Question 8
    1 / -0
    In the Haber process of synthesis of $$NH_3$$,  which of the following statement is correct?
    Solution

    Preparation of Ammonia: 

    $$N_2 + 3H_2\rightarrow 2NH_3$$

    At high pressure about 200-250 atm, and a moderate temperature of $$750K$$, the reaction takes place. Removal of ammonia is done by liquefaction, In the process, iron is used as a catalyst and molybdenum as a promoter.

  • Question 9
    1 / -0
    When plants and animals decay, the organic nitrogen is converted into inorganic nitrogen. The inorganic nitrogen is in the form of:
    Solution
    When plants and animals decay, the organic nitrogen is converted into inorganic nitrogen. The inorganic nitrogen is in the form of ammonia $$\displaystyle NH_3$$.
  • Question 10
    1 / -0
    Which one of the following statements is incorrect?
    Solution
    All interhalogens have weaker $$X-X'$$ bonds and not $$X-X$$ bonds but F is an exception due to high electronegativity and small size. 

    Hence, option (A) is incorrect.
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