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Coordination Co...

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  • Question 1
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    A complex compound of cobalt has molecular formula containing five $$NH_{3}$$ molecules, one $$NO_{2}$$ group and two $$Cl$$ atoms for one $$Co$$ atom. One mole of this compound produces three moles of ions in aqueous solution. On reacting with an excess of $$AgNO_{3}$$ solution, two moles of $$AgCl$$ get precipitated. The ionic formula of the compound is:

  • Question 2
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    The total number of possible coordination isomers of the complex compound $$\left [ Cu\left ( NH_{3} \right )_{4} \right ]\left [ PtCl_{4} \right ]$$ are:

  • Question 3
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    Which of the following statements is incorrect?

  • Question 4
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    Which pair is correctly matched?

  • Question 5
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    Match column-I (chemical composition of precipitates) with column-II (colour of the precipitate) and select the correct answer using the codes given below in the columns :
    (a) $$Co [Hg (SCN)_4]$$         (p) black
    (b) $$Fe_3[Fe(CN)_6]_2$$         (q) rosy red
    (c) $$Ni(dmg)_2$$                   (r) prussian blue

    (d) PbS                             (s) deep blue

  • Question 6
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    In the analysis of an organic compound, it was found that it contains 7 carbon atoms, there are two C = C bonds and one $$C\equiv C$$ bond. This compound is a hydrocarbon. Hydrocarbons have only carbon and hydrogen elements. On structural analysis it was found that it is covalent in nature and expected structure is given above. The ratio between the pure and hybrid orbitals is?

  • Question 7
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    Which of the following orbitals can not undergo hybridisation amongst themselves?
    $$(I)\ 3d, 4s$$ 

    $$(II)\ 3d, 4d$$ 
    $$(III)\ 3d, 4s$$ & $$4p $$ 
    $$(IV) \ 3s, 3p$$ & $$4s$$

  • Question 8
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    Which of the following statements is incorrect?

  • Question 9
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    For the dark green compound, $$ CrCl_3. 6H_2O$$, which of the following is correct?

  • Question 10
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    Directions For Questions

    Double salts are addition compounds which lose their identity in aqueous solution whereas complexes which are also addition compounds do not lose their identity in aqueous solution. The coordination compounds show isomerism and find applications in photography, qualitative analysis, metallurgy, water purification and in the treatment of various diseases.

    ...view full instructions

    Which of the following statement is true for the complex, $$[Co(NH_3)_4Br_2]NO_2?$$

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