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Atoms Test - 33

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Atoms Test - 33
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  • Question 1
    1 / -0
    A beam of $$13.0\space eV$$ electrons is used to bombard gaseous hydrogen. The series obtained in emission spectra is/are
    Solution
    For $$13.0\ eV$$ we can expect emissions from any of the lines, Lyman, Balmer, Paschen , Brackett, Pfund, since all their energies lie within $$13\ eV$$.
  • Question 2
    1 / -0
    Which of the following is true when Bohr gave his model for hydrogen atom?
    Solution

    Niels Bohr introduced the atomic Hydrogen model in 1913. He described it as a positively charged nucleus, comprised of protons and neutrons, surrounded by a negatively charged electron cloud. In the model, electrons orbit the nucleus in atomic shells. The atom is held together by electrostatic forces between the positive nucleus and negative surroundings.

    Bohr’s Postulates

    1. An atom has a number of stable orbits in which an electron can reside without the emission of radiant energy. Each orbit corresponds, to a certain energy level.

    2. An electron may jump spontaneously from one orbit (energy level E1) to the other orbit (energy level E2) (E> E1); then the energy change AE in the electron jump is given by Planck’s equation

    ∆E = E2-E1 = hv

    Where h = Planck’s constant.

    And v = frequency of light emitted.

    3. The motion of an electron in a circular orbit is restricted in such a manner that its angular momentum is an integral multiple of h/2π, Thus

    mvr = nh/2π, where m = mass of the electron

    v = velocity of the electron

    r = radius of the orbit an

    n = an integer called principal quantum number of the electron.:

    4. A special surface around nucleus which contained orbits of equal energy and radius was called shell. These shells are numbered from inside to outwards as 1, 2, 3, 4 etc. and called K, L, M, N etc., respectively.

     


  • Question 3
    1 / -0
    Difference between $$nth$$ and $$(n+1)th$$ Bohr's radius of hydrogen atom is equal to $$(n-1)th$$ Bohr's radius. The value of $$n$$ is
    Solution
    Given,
    $${ \left( n+1 \right)  }^{ 2 }-{ n }^{ 2 }={ \left( n-1 \right)  }^{ 2 }\\ \Rightarrow 1+2n={ n }^{ 2 }+1-2n\\ \Rightarrow { n }^{ 2 }=4n\\ \Rightarrow n=4$$ 
  • Question 4
    1 / -0
    The radius of hydrogen atom in the ground state is $$5.3\times10^{-11} m$$. When struck by an electron, its radius is found to be $$21.2\times10^{-11}m$$. The principal quantum number of the final state will be
    Solution
    From the concept attached:
    $$ r \propto n^2$$
    For $$n=1$$ if $$r_1 =5.3 \times 10^{-11}m$$
    Then, $$r = 21.4 \times 10^{-11} = 4r_1 = 2^2 r_1$$ so $$n =2$$
  • Question 5
    1 / -0
    If elements with principal quantum number $$n>4$$ were not allowed in nature, the number of possible elements would have been
    Solution
    $$\textbf{Hint}$$:The total number of possible electronic configurations will give total number of elements.

    $$\textbf{Step1:Number of elements}$$
    The number of electrons that can fill a shell is given by twice the square of the quantum number of that shell. The total number of possible electronic configurations will give the total number of elements.
    $$N=2n^2$$
    where NN is the number of electrons in a particular orbit or number of possible electronic configurations and nn is the quantum number of the orbit.

    $$\textbf{Step2:Put values of n}$$
    For first orbit n=1
    $$N=2(2^1)$$=4

    For second orbit n=2
    $$N=2(2^2)$$=8

    For third orbit n=3
    $$N=2(2^3)$$=16

    For fourth orbit n=4
    $$N=2(2^4)$$=32

    Hence the total number of electronic configurations are=$$4+8+16+32=60$$
    So total number of elements are =60.
  • Question 6
    1 / -0
    The velocity of an electron in the first orbit of $$H$$ atom is $$'v\ '$$. The velocity of an electron in the second orbit of $$He^+$$ is
    Solution
    For hydrogen:
    Angular momentum $$=mvr=\dfrac{nh}{2\pi}$$
    $$v=\dfrac{nh}{mr2\pi}$$
    $$r=0.529\dfrac{n^2}{Z}$$

    So, $$v=\dfrac{Zh}{0.529mn2\pi}$$

    For hydrogen $$Z=1,n=1$$
    $$v=\dfrac{h}{0.529m2\pi}$$

    For $$He^+$$ $$Z=2 ,n=2$$
    $$v_1=\dfrac{2h}{0.529m\times 2\times 2\pi}=v$$
  • Question 7
    1 / -0
    How can the rate of emission of electrons in a cathode ray tube can be increased?
    Solution
    Rate of emission of electrons can be increased by increasing the temperature and temperature of cathode can be increased by increasing the filament current. 
  • Question 8
    1 / -0
    In a cathode ray tube, what is the effect on the beam of particles if the anode voltage is increased ?
    Solution
    Electrons emitted by the cathode are attracted to the focusing anode if the anode voltage is increased.
    Thus, Kinetic Energy of electron beam increase.
  • Question 9
    1 / -0
    In a cathode ray tube, what is the effect on the beam of particles if a hotter filament is used ?
    Solution
    Hotter filament will increase the temperature.
    Hence rate of electron emission will increase.
  • Question 10
    1 / -0
    State the approximate potential difference applied between the anode and filament cathode ray tube .
    Solution
    The electrons are accelerated by a second anode at high potential, more than 500 V.
    So, the answer is option (A).
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