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Atoms Test - 60

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Atoms Test - 60
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  • Question 1
    1 / -0
    Wavelength of the first line of Balmer series is $$600nm$$. The wavelength of second line of the Balmer series will be:
    Solution
    $$\dfrac{1}{\lambda_1} = R \left[\dfrac{1}{2^2} - \dfrac{1}{3^2}\right] = \dfrac{5}{36}R$$
    $$\dfrac{1}{\lambda_2} = R\left[\dfrac{1}{2^2} - \dfrac{1}{4^2} \right] = R \left[\dfrac{3}{16}\right]$$
    $$\dfrac{\lambda_2}{\lambda_1} = \dfrac{5R/36}{3R/16} = \dfrac{5}{36}\times \dfrac{16}{3}$$
    $$\lambda_2 = \dfrac{5}{36}\times \dfrac{16}{3}\times 660 = 444.44nm$$
  • Question 2
    1 / -0
    Ionized hydrogen atoms and $$\alpha$$-particles with same momenta enters perpendicular to a constant magnetic field, B. The ratio of their radii of their paths $$r_H : r_{\alpha}$$ will be :
    Solution
    We know,
    $$r_H = \dfrac{P}{e\times B}$$

    $$r_{\alpha} = \dfrac{P}{2e\times B}$$(As $$\alpha$$ has 2e of charge on it)

    $$\dfrac{r_H}{r_{\alpha}} = \dfrac{\dfrac{P}{eB}}{\dfrac{P}{2eB}}$$

    $$\implies \dfrac{r_H}{r_{\alpha}} = \dfrac{2}{1}$$
    Hence option A is correct answer
  • Question 3
    1 / -0
    The total energy of an electron revolving in the second orbit of hydrogen atom is?
    Solution
    $$E_n=\dfrac{-13.6z^2}{n^2}$$
    $$Z=1; n=2; E_n=-3.4eV$$.
  • Question 4
    1 / -0
    The period of revolution of an electron in the ground state of hydrogen atom is T. The period of revolution of the electron in the first excited state is?
    Solution
    $$T^2\alpha R^3\alpha n^6\Rightarrow T\alpha n^3$$
    Hence $$\dfrac{T^1}{T}=2^3=8$$.
  • Question 5
    1 / -0
    In $$H$$-atm spectrum $$V$$ is the wave number
    $$V_1 = V_{min} + V_{max}$$ for Lyman series
    $$V_1 = V_{min} + V_{max}$$ for Balmer series then $$V_1 : V_2$$
    Solution
    $$V_1 = R (1)^2 \left[\dfrac{1}{1^2} - \dfrac{1}{2^2}\right] + R(1)^2 \left(\dfrac{1}{1^2} - \dfrac{1}{\infty^2}\right) = R Z^2\left(\dfrac{7}{4}\right)$$
    $$V_2 = R (1)^2 \left[\dfrac{1}{2^2} - \dfrac{1}{3^2}\right] + R(1)^2 \left(\dfrac{1}{2^2} - \dfrac{1}{\infty^2}\right) = R (1)^2\left(\dfrac{7}{18}\right)$$
    $$V_1 : V_2 = 9 : 2$$
  • Question 6
    1 / -0
    An excited $$He^+$$ ion emits two photons in succession, with wavelengths $$108.5 nm$$ and $$30.4 nm$$, in making a transition to ground state. The quantum number $$n$$, corresponding to its initial excited state is (for photon of wavelength $$\lambda$$, energy $$E = \dfrac{1240 eV}{\lambda (in\, nm)}$$)
    Solution
    $$\dfrac{1}{\lambda} = R \left(\dfrac{1}{m^2} - \dfrac{1}{n^2}\right)z^2$$
    $$\dfrac{1}{1085} = R \left(\dfrac{1}{m^2} - \dfrac{1}{n^2}\right)^2$$
    $$\dfrac{1}{304} = R \left(\dfrac{1}{1^2} - \dfrac{1}{m^2}\right)2^2$$
    $$\therefore m = 2$$
    $$\therefore n = 5$$
  • Question 7
    1 / -0
    The number density of molecules of a gas depends on their distance $$r$$ from the origin as, $$n(r) = n_0 e^{-\alpha r^4}$$. Then the total number of molecules is proportional to:
    Solution
    Given number density of molecules of gas as a function of $$r$$ is

    $$n(r) = n_0 e^{-\alpha r^4}$$

    $$\therefore$$ Total number of molecule $$= \overset{\infty}{\underset{0}{\int}} n(r) dV$$

    $$= \overset{\infty}{\underset{0}{\int}} n_9 e^{-\alpha r^4} 4\pi r^2 dr$$

    $$\therefore$$ Number of molecules is proportional to $$n_0 \alpha^{-3/4}$$
  • Question 8
    1 / -0
    The ratio of mass densities of nuclei of $$^{40} Ca$$ and $$^{16} O$$ is close to :
    Solution
    $$\rho= \dfrac{Mass}{Volume}$$

    $$r = r_0 A^{\dfrac {1}{3}}$$ 
       r = radius of nucleus
       A = Atomic number
    $$r_0 = constant$$
                                                 
    $$\rho = \dfrac{Mass}{\dfrac{4}{3}\pi r^3}$$

    $$\rho \propto \dfrac{Mass(Z)}{A}$$
    For, Oxygen, Z=16, A=8
           Calsium, Z=40, A=20
    $$\dfrac{\rho_{o_{2}}}{\rho_{ca}}=\dfrac{Z_{o_{2}}}{Z_ca}=\dfrac{16}{8}\times \dfrac{20}{40} = \dfrac{1}{1}$$
  • Question 9
    1 / -0
    Taking the wavelength of first Balmer line in hydrogen spectrum ($$n=3$$ to $$n=2$$) as $$660nm$$, the wavelength of the 2nd Balmer line ($$n=4$$ to $$n=2$$) will be:
    Solution
    $$\cfrac { 1 }{ 660 } =R\left( \cfrac { 1 }{ { 2 }^{ 2 } } -\cfrac { 1 }{ { 3 }^{ 2 } }  \right) =\cfrac { 5R }{ 36 } ....(1)\quad $$
    $$\cfrac { 1 }{ \lambda  } =R\left( \cfrac { 1 }{ { 2 }^{ 2 } } -\cfrac { 1 }{ { 4 }^{ 2 } }  \right) =\cfrac { 3R }{ 16 } ....(2)\quad \quad $$
    dividing (1) with (2)
    $$\cfrac { \lambda  }{ 660 } =\cfrac { 5\times 16 }{ 36\times 3 } $$
    $$\lambda =\cfrac { 4400 }{ 9 } =488.88=488.9nm$$
  • Question 10
    1 / -0
    In $$Li^{++}$$, electron in first Bohr orbit is excited to a level by a radiation of wavelength $$\lambda$$. when the ion gets deexcited to the ground state in all possible ways (including intermediate emissions), a total of six spectral lines are observed. What is the value of $$\lambda$$ ?
    (Given : $$h = 6.63 \times 10^{34} Js$$;  $$ \, c = 3 \times 10^8 ms^{-1}$$)
    Solution
    $$\Delta E = \dfrac{hc}{\lambda}$$
    $$13.6 \times 9 - 0.85 \times 9 = \dfrac{hc}{\lambda}$$
    $$\lambda = \dfrac{hc}{9 \times (13.6 - 0.85) eV}$$
    $$= \dfrac{1240 eV . nm}{9 \times 12.75 eV}$$
    $$\lambda = 10.8 nm$$

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