Self Studies

States of Matte...

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  • Question 1
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    The surface tension of which of the following liquids is the maximum?

  • Question 2
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    The vapor pressure of different substances at the same temperature increases if

  • Question 3
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    Dipole-dipole forces act between the molecules possessing permanent dipole. Ends of dipoles possess ‘partial charges’. The partial charge is

  • Question 4
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    The enthalpies of vaporisation of H2O, C2H5OH and CS2 are 40.6, 38.6 and 26.8 kJ/mol, respectively. The decreasing order of intermolecular forces in these liquids is:

  • Question 5
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    A student forgot to add the reaction mixture to the round bottomed flask at 27 °C , but instead he/she placed the flask on the flame. After a lapse of time, he realized his mistake, and using a pyrometer he found the temperature of the flask was 477 °C. What fraction of air would have been expelled out?

  • Question 6
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    Consider the following graph.



    Which of the following statements is wrong?

  • Question 7
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    What will be the minimum pressure required to compress 500 dm3of air at 1 bar to 200 dm3at 30°C?

  • Question 8
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    Dipole–induced dipole interactions are present in which of the following pairs?

  • Question 9
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    The interaction energy of London force is inversely proportional to sixth power of the distance between two interacting particles, but their magnitude depends upon

  • Question 10
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    Which of the following substances, when dissolved in water, increases the surface tension of water?

  • Question 11
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    For hydrogen gas, the values of Van der Waals constants 'a' and 'b' are 0.245 atm litre2 mol-2 and 0.026 litre mol-1, respectively. Calculate the volume of 1 mol of hydrogen at 5 atm and 0oC.

  • Question 12
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    Which of the following properties of water can be used to explain the spherical shape of rain droplets?

  • Question 13
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    Calculate the weight of CH4 in a 9 litre cylinder at 16 atm and 27oC.
    (R = 0.08 L atm/K)

  • Question 14
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    What is the dominate intermolecular force that must be overcome in converting liquid CH3OH into gas?

  • Question 15
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    In order to increase the volume of a gas by 10%, the pressure of the gas should be

  • Question 16
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    100 ml of a gas diffuses in the same time as 75 ml of ammonia at 30oC and 743 torr. What is the molecular mass of the gas?

  • Question 17
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    For a Van der Waals gas, the expression for Boyle's temperature is

  • Question 18
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    What will happen to the volume of a bubble of air found under water in a lake, where the temperature is 15oC and the pressure is 1.5 atm, if the bubble rises to the surface where the temperature is 25oC and the pressure is 1.0 atm?

  • Question 19
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    If 10-4 dm3 of water is introduced into a 1.0 dm3 flask at 300 K, then how many moles of water are in the vapour phase when the equilibrium is established?

    (Given: Vapour pressure of H2O at 300 K is 3170 Pa and R = 8.314 J K-1 mol-1)

  • Question 20
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    The van der Waals Equation adjusts the measured volume

  • Question 21
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    The van der Waals Equation adjusts the measured pressure

  • Question 22
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    The interaction energy of London force is inversely proportional to sixth power of the distance between two interacting particles but their magnitude depends upon

  • Question 23
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    68 ml of a sample of nitrogen is collected over water at 20oC and 700 mm of Hg. The volume of dry nitrogen at STP is
    [The aq. tension of water is 17.5 mm of Hg at 20oC.]

  • Question 24
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    A person living in Shimla observed that cooking food without using pressure cooker takes more time. The reason for this observation is that at high altitude:

  • Question 25
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    A gas in outer space is at a pressure of 5 x 10-14 torr. When the temperature is constant, how much outer space could you compress into 1 dm3 box at 1 atmosphere?

  • Question 26
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    An open vessel at 37oC is heated until 3/5 of the air in it has been expelled. Assuming that the volume of the vessel remains constant, the temperature to which the vessel is heated is

  • Question 27
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    Which of the following property of water can be used to explain the spherical shape of rain droplets?

  • Question 28
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    Equal weights of ethane and hydrogen are mixed in an empty container at 25oC. Determine the fraction of total pressure exerted by hydrogen.

  • Question 29
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    Choose the incorrect statement.

  • Question 30
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    As the temperature increases, average kinetic energy of molecules increases. What would be the effect of increase of temperature on pressure provided the volume is constant?

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