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The vapor pressure of different substances at the same temperature increases if
Vapour pressure of a substance is inversely proportional to the intermolecular forces between molecules.
Dipole-dipole forces act between the molecules possessing permanent dipole. Ends of dipoles possess ‘partial charges’. The partial charge is
Partial charge is a small charge developed by displacement of electrons. It is less than unit electronic charge and is represented as δ+ or δ–
A student forgot to add the reaction mixture to the round bottomed flask at 27 °C , but instead he/she placed the flask on the flame. After a lapse of time, he realized his mistake, and using a pyrometer he found the temperature of the flask was 477 °C. What fraction of air would have been expelled out?
What will be the minimum pressure required to compress 500 dm3of air at 1 bar to 200 dm3at 30°C?
Using ideal gas equation, PV=nRT,since T is constant, we haveP1V1 = P2V2 i.e.500 dm3 ×1bar = 200dm3×P2which gives P2= 2.5 bar
The van der Waals Equation adjusts the measured volume
nb is subtracted.where, the constant b is called co-volume or excluded volume per mole of a gas. it measure the effective size of gas molecule (V-nb)
The van der Waals Equation adjusts the measured pressure
(an2) ÷ V2 term term is added, where constant 'a' is gives the magnitude of attractive forces between gas molecules.
The interaction energy of London force is inversely proportional to sixth power of the distance between two interacting particles but their magnitude depends upon
London dispersion forces operate only over very short distance. The energy of interaction varies as 1/(distance between two interacting particles)6. Large or more complex are the molecules, greater is the magnitude of London forces. This is obviously due to the fact that the large electron clouds are easily distorted or polarised. Hence, greater the polarisability of the interacting particles, greater is the magnitude of the interaction energy.
A person living in Shimla observed that cooking food without using pressure cooker takes more time. The reason for this observation is that at high altitude:
As we move to higher altitude, the atmospheric pressure decreases. Therefore, boiling point of water also decreases, hence , cooking of food takes longer time without using pressure cooker.
Which of the following property of water can be used to explain the spherical shape of rain droplets?
Due to surface Tension, the water droplet tends to acquire minimum surface area, hence water droplet attains spherical shape.
As the temperature increases, average kinetic energy of molecules increases. What would be the effect of increase of temperature on pressure provided the volume is constant?
P α T at constant volume.This is according to Gay Lussac’s law-“ At constant volume, the pressure of a given mass of a gas is directly proportional to its absolute temperature.”
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