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Haloalkanes and Haloarenes Test - 3

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Haloalkanes and Haloarenes Test - 3
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  • Question 1
    1 / -0

    Upon oxidation, one of the following halogen-containing compounds forms an extremely poisonous gas – – + O2  → 2 COCl2 + 2HCl

    Solution

    CHCl3 on reaction with oxygen forms phosgene. Chloroform decomposes when it exposed to sunlight.it decomposes to a harmful gas phosgene(COCl2) Chloroform decomposes when it exposed to sunlight.it decomposes to a harmful gas phosgene(COCl2)

     

  • Question 2
    1 / -0

    Hydrocarbons having double the number of carbon atoms than present in the original alkyl halide are produced by using

    Solution

    The Wurtz reaction, named after Charles-AdolpheWurtz, is a coupling reaction in organic chemistry, organometallic chemistry and recently inorganic main group polymers, whereby two alkyl halides arereacted with sodium metal in dry ethereal solution to form a higher alkane:

     

  • Question 3
    1 / -0

    Which of the following has the highest melting point?

  • Question 4
    1 / -0

    Upon oxidation, one of the following halogen-containing compounds forms an extremely poisonous gas – – + O2  → 2 COCl2 + 2HCl

    Solution

    CHCl3 on reaction with oxygen forms phosgene. Chloroform decomposes when it exposed to sunlight.it decomposes to a harmful gas phosgene(COCl2) Chloroform decomposes when it exposed to sunlight.it decomposes to a harmful gas phosgene(COCl2)

     

  • Question 5
    1 / -0

    Carbon – halogen bond of alkyl halides is responsible for their nucleophilic substitution, elimination and their reaction with metal atoms to form organometallic compounds because of its

    Solution

    Since halogen atoms are more electronegative than carbon, the carbon-halogen bond of alkyl halide is polarised; the carbon atom bears a partial positive charge whereas the halogen atom bears a partial negative charge. This is responsible for nucleophilic substitution reactions, elimination reactions and reaction of alkyl hlides with a metal to form organometallic compounds.

     

  • Question 6
    1 / -0

    The following question has four choices out of which ONLY ONE is correct.

    The molecular formula of chloropicrin is

  • Question 7
    1 / -0

    The following question has four choices out of which ONLY ONE is correct.

    C - Cl bond is stronger than C - I bond because 

  • Question 8
    1 / -0

    Which of the following statements is incorrect for freons?

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