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Coordination Compounds Test - 3

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Coordination Compounds Test - 3
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  • Question 1
    1 / -0.25

     

    Which of the following can be termed as mixed complex?

     

    Solution

     

     

    In A one and more different types of ligands are present.

     

     

  • Question 2
    1 / -0.25

     

    Which of the following ligand gives chelate complexes?

     

    Solution

     

     

    Oxalate is a bidentate ligand.

     

     

  • Question 3
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    In the formation of complex entity, the central atom/ion acts as

     

    Solution

     

     

    Central Metal ion behave as a Lewis Acid while Ligand act as a lewis Base.

     

     

  • Question 4
    1 / -0.25

     

    Which of the following is a negative ligand?

     

    Solution

     

     

    C5 H5 a negative ligand.

     

     

  • Question 5
    1 / -0.25

     

    The correct IUPAC name of  Mn3 (C0)12  is

     

    Solution

     

     

    Ligands are named  1st  followed by the name of central metal ion.

     

     

  • Question 6
    1 / -0.25

     

    Which is used in cancer therapy?

     

    Solution

     

     

    Cis Platin (cis – [Pt(NH3 )2 (Cl)2 ] is a anti cancer drug.

     

     

  • Question 7
    1 / -0.25

     

    The IUPAC name of AlCl3 .4(EtOH) is

     

    Solution

     

     

    This is double salt so name is written in sequential manner.

     

     

  • Question 8
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    Sodium pentacyanonitrosylferrate(II) is also called?

     

    Solution

     

     

    Na2 [Fe(CN)5 NO] is Sodium nitroprusside.

     

     

  • Question 9
    1 / -0.25

     

    A complex involving dsp2  hybridization has

     

    Solution

     

     

    dsp2 is square planar geometry.

     

     

  • Question 10
    1 / -0.25

     

    In the complex  Fe(CO)x , the value of x is

     

    Solution

     

     

    Complex carbonyls follow Sidwick 's EAN rule i.e compound with EAN 36 will be relatively more stable than other metal carbonyls. Iron pentacarbonyl has EAN number of  36 = Z −X+Y = (26 −0+2x)
    [Z = atomic number, X = oxidation state of metal, Y= total electrons donated by ligand]
    ∴x = 5. So, the formula will be  Fe(CO)5.

     

     

  • Question 11
    1 / -0.25

     

    Which among the following has square pyramidal geometry?

     

    Solution

     

     

    Bis(acetylacetonato)oxovanadium(IV) has square pyramidal geometry.

     

     

  • Question 12
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    The hybridization of nickel in tetracarbonyl nickel is

     

    Solution

     

     

    [Ni(CO)4 ] has tetrahedral geometry so hybridisation is sp3

     

     

  • Question 13
    1 / -0.25

     

    According to Werner ’s theory , the primary valences of the central atom

     

    Solution

     

     

    Primary valency is equal to no. of ligands attachted which are negatively charges.

     

     

  • Question 14
    1 / -0.25

     

    The EAN of Ni in [Ni(CN)4 ]2--  is

     

    Solution

     

     

    EAN = 28 (Z) –2 (oxidation number) + 2*4 (CN) = 34

    Hence A

     

     

  • Question 15
    1 / -0.25

     

    In the complex PtCl4 .3NH3  the number of ionisable chlorines is

     

    Solution

     

     

    The complex  [PtCl3 (NH3 )3 ]Cl  has only one ionisable chlorine

     

     

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