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Thermodynamics ...

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  • Question 1
    4 / -1

    For a reversible reaction,
    X (g) + 3Y (g) ⇌ 2Z(g); ∆H = - 40 kJ, the standard entropies of X ,Y and Z are 60, 40 and 50 JK-1 mol-1 respectively. The temperature at which the above reaction attains equilibrium is about

  • Question 2
    4 / -1

    The decomposition of limestone
    CaCO3 (g) ⇌ CaO(s) + CO2 (g)
    is non-spontaneous at 298 K. The ∆H° and ∆S° values for the reaction are 76.0 kJ and 60 JK-1 respectively. At what temperature the decomposition becomes spontaneous ?

  • Question 3
    4 / -1

    Identify the correct statement regarding a spontaneous process.

  • Question 4
    4 / -1

    In conversion of limestone to lime,
    CaCO3 (s) → CaO(s) + CO2 (g )
    the values of ∆H° and ∆S °are + 179.1 kJ mol-1 and 160.2 J/K respectively at 298 K and 1 bar. Assuming that ∆H° and ∆S ° do not change with temperature, temperature above which conversion of limestone to lime will be spontaneous is

  • Question 5
    4 / -1

    Standard enthalpy and standard entropy changes for the oxidation of ammonia at 298 K are - 382.64 kJ mol-1 and - 145.6 JK-1 mol-1, respectively. Standard Gibbs energy change for the same reaction at 298 K is

  • Question 6
    4 / -1

    Which of the following is correct for the reaction ∆H = +ve and ∆S = +ve?

  • Question 7
    4 / -1

    What is the relation between E° and K ?

  • Question 8
    4 / -1

    A schematic plot of In Keq versus inverse of temperature for a reaction is shown below

  • Question 9
    4 / -1

    The enthalpy change for the transition of liquid water to steam is 40.8 kJ per mol at 100°C. The entropy change for the process will be

  • Question 10
    4 / -1

    If an endothermic reaction is non-spontaneous at freezing point of water and becomes feasible at its boiling point, then

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