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  • Question 1
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    Which of the following methods is suitable for preventing an iron frying pan from rusting?

  • Question 2
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    The basic unit of nucleic acid is ___________.

  • Question 3
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    Exactly \(1 {~g}\) of urea dissolved in \(75 {~g}\) of water gives a solution that boils at \(100.114^{\circ} {C}\) at 760 torr. The molecular weight of urea is \(60.1\). The boiling point elevation constant for water is:

  • Question 4
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    The stepwise formation of \(\left[\mathrm{Cu}\left(\mathrm{NH}_3\right)_4\right]^{2+}\) is given below

    \(\mathrm{Cu}^{2+}+\mathrm{NH}_3 \stackrel{\mathrm{K}_1}{\rightleftharpoons}\left[\mathrm{Cu}\left(\mathrm{NH}_3\right)_2\right]^{2+} \)

    \( {\left[\mathrm{Cu}\left(\mathrm{NH}_3\right)^{2+}+\mathrm{NH}_3 \stackrel{\mathrm{K}_2}{\rightleftharpoons}\left[\mathrm{Cu}\left(\mathrm{NH}_3\right)_2\right]^{2+}\right.} \)

    \({\left[\mathrm{Cu}\left(\mathrm{NH}_3\right)_2\right]^{2+}+\mathrm{NH}_3 \stackrel{\mathrm{K}_3}{\rightleftharpoons}\left[\mathrm{Cu}\left(\mathrm{NH}_3\right)_3\right]^{2+}} \)

    \({\left[\mathrm{Cu}\left(\mathrm{NH}_3\right)_3\right]^{2+}+\mathrm{NH}_3 \stackrel{\mathrm{K}_4}{\rightleftharpoons}\left[\mathrm{Cu}\left(\mathrm{NH}_3\right)_4\right]^{2+}}\)

    The value of stability constants \(\mathrm{K}_1, \mathrm{~K}_2, \mathrm{~K}_3\) and \(\mathrm{K}_4\) are \(10^4, 1.58 \times 10^3, 5 \times 10^2\) and \(10^2\) respectively. The overall equilibrium constants for dissociation of \(\left[\mathrm{Cu}\left(\mathrm{NH}_3\right)_4\right]^{2+}\) is \(\mathrm{x} \times 10^{-12}\). The value of \(\mathrm{x}\) is________(Rounded off to the nearest integer)

  • Question 5
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    Which of the statements about the reaction below are incorrect?

    \(2 P b O(s)+C(s) \rightarrow 2 P b(s)+C O_{2}(g)\)

    (a) Lead is getting reduced.

    (b) Carbon dioxide is getting oxidised.

    (c) Carbon is getting oxidised.

    (d) Lead oxide is getting reduced.

  • Question 6
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    Among the lanthanides, the one obtained by synthetic method is:

  • Question 7
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    An aqueous solution containing \(0.25\) moles of non-volatile but strong electrolytes solute \(X\) in \(500 \mathrm{~g}\) water freeze at \(-2.79^{0} \mathrm{C}\). The number of ions furnished in water per formula unit of \({X}\) is \(\left(K_{f}=\right.\) \(1.86\) )

  • Question 8
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    The increasing order of the first ionisation enthalpies of the elements B, P, S and \(\mathrm{F}\) (lowest first) is:

  • Question 9
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    The complex \(\left[ Co \left( NH _{3}\right)_{5}\left( NO _{2}\right)\right]^{2+}\) and \(\left[ Co \left( NH _{3}\right)_{5}( ONO )\right]^{2+}\) are called:

  • Question 10
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    Ionic species are stabilised by the dispersal of charge, which of the following carboxylate ions is the most positive charge?

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