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Chemistry Test ...

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  • Question 1
    1 / -0

    In the reaction \(4 \mathrm{Fe}+3 \mathrm{O}_{2} \rightarrow 4 \mathrm{Fe}^{3+}+6 O^{2-}\) which of the following statements is incorrect?

  • Question 2
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    Calculate e.m.f of the following cell at \(298 \mathrm{~K}\) :

    \(2 \mathrm{Cr}(\mathrm{s})+3 \mathrm{Fe}^{2+}(0.1 \mathrm{M}) \rightarrow 2 \mathrm{Cr}^{3+}(0.01 \mathrm{M})+3 \mathrm{Fe}(\mathrm{s})\)

    Given: \(\mathrm{E}^{\circ}\left(\mathrm{Cr}^{3+} \mid \mathrm{Cr}\right)=-0.74 \mathrm{VE}^{\circ}\left(\mathrm{Fe}^{2+} \mid \mathrm{Fe}\right)=-0.44 \mathrm{~V}\)

  • Question 3
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    The helical structure of protein is stabilized by:

  • Question 4
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    Match the following :

    Test/Method   Reagent
    (i) Lucas Test   (a) \(\mathrm{C}_6 \mathrm{H}_5 \mathrm{SO}_2 \mathrm{Cl} /\) aq. \(\mathrm{KOH}\)
    (ii) Dumas method  (b) \(\mathrm{HNO}_3 / \mathrm{AgNO}_3\) 
    (iii) Kjeldahl’s method  (c) \(\mathrm{CuO} / \mathrm{CO}_2\) 
    (iv) Hinsberg test   (d) \(\mathrm{Conc} . \mathrm{HCl}\) and \(\mathrm{ZnCl}_2\)(I
       (e) \(\mathrm{H}_2 \mathrm{SO}_4\)

  • Question 5
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    L-isomer of tetrose \(\mathrm{X}\left(\mathrm{C}_4 \mathrm{H}_8 \mathrm{O}_4\right)\) gives positive schiff's test and has two chiral carbons. On acetylation. ' \(\mathrm{X}\) ' yields triacetate. ' \(\mathrm{X}\) ' undergoes following reactions

    ' \(\mathrm{X}\) ' is

  • Question 6
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    \(1.22 \mathrm{~g}\) of an organic acid is separately dissolved in \(100 \mathrm{~g}\) of benzene \(\left(\mathrm{K}_{\mathrm{b}}=2.6 \mathrm{~K} \mathrm{~kg} \mathrm{~mol}^{-1}\right)\) and \(100 \mathrm{~g}\) of acetone \(\left(\mathrm{K}_{\mathrm{b}}=1.7 \mathrm{Kkg} \mathrm{mol}^{-1}\right)\). The acid is known to dimerise in benzene but remain as a monomer in acetone. The boiling point of the solution in acetone increases by \(0.17^{\circ} \mathrm{C}\). The increase in boiling point of solution in benzene in \({ }^{\circ} \mathrm{C}\) is \(\mathrm{x} \times 10^{-2}\). The value of \(\mathrm{x}\) is....... (Nearest integer)

    [Atomic mass: \(\mathrm{C}=12.0, \mathrm{H}=1.0, \mathrm{O}=16.0\) ]

  • Question 7
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    For a 1st order reaction, if the concentration is doubled then the rate of reaction becomes:

  • Question 8
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    When \(\mathrm{KMnO}_{4}\) solution is added to oxalic acid solution, the decolourisation is slow in the beginning but becomes instantaneous after some time because:

  • Question 9
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    Which of the following statement is correct?

  • Question 10
    1 / -0

    For the process to occur under adiabatic conditions, the correct conditionis:

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