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Chemistry Test ...

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  • Question 1
    4 / -1

    The electronic configuration of an element is \(1 \mathrm{s}^{2}, 2 \mathrm{s}^{2}, 2 \mathrm{p}^{6}, 3 \mathrm{s}^{2}, 3 \mathrm{p}^{3} .\) Which is the atomic number of the element which is just below the above element in the periodic table?

  • Question 2
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    A copper strip having \(3 \mathrm{~cm}\) length and \(4 \mathrm{~cm}\) breadth is coated with silver of \(2 \mathrm{~mm}\) thickness. Calculate the quantity of electricity (in coulomb) required for the above process. (Density of \(\mathrm{Ag}=10.5 \mathrm{~g} \mathrm{~cm}^{-3}\) )

  • Question 3
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    The species present in solution when \(\mathrm{C} \mathrm{O}_{2}\) is dissolved in water are:

  • Question 4
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    In acidic medium, \(\mathrm {H_{2} O_{2}}\) changes \(\mathrm {C r_{2} O_{7}^{2-}}\) to \(\mathrm {C r O_{5}}\) which has two (-O-O-) bonds. Oxidation state of \(\mathrm{Cr}\) in \(\mathrm{Cr} O_{5}\) is:

  • Question 5
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    The dipole moment of \(H B r\) is \(2.6 \times 10^{-30} C-m\) and the interatomic spacing is \(1.41 \mathring A\). The percentage of ionic character in \(H B r\) is:

  • Question 6
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    Acetamide is treated with the following reagents separately. Which one of these would yield methylamine?

  • Question 7
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    A compound \(X\) on heating gives a colourless gas. The residue is dissolved in water to obtain Y. Excess carbon dioxide is bubbled through an aqueous solution of \(\mathrm{Y} ; \mathrm{Z}\) is formed. \(Z\) on gently heating gives back \(X\). The compound \(X\) is:

  • Question 8
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    Identify the incorrect statement regarding heavy water:

  • Question 9
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    The compound insoluble in acetic acid is:

  • Question 10
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    First and second ionization energies of Magnesium are \(7.646\) and \(15.035 \mathrm{eV}\) respectively. The amount of energy in \(\mathrm{kJ}\) needed to convert all the atoms of Magnesium into \(\mathrm{Mg}^{2+}\) ions present in \(12\ \mathrm{mg}\) of Magnesium vapours is:

    (Given \(1\ \mathrm{eV}=96.5 \mathrm{~kJ} / \mathrm{mol}\))

  • Question 11
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    \(6.2 \mathrm{~g}\) of a sample containing \(\mathrm{Na}_{2} \mathrm{CO}_{3}, \mathrm{NaHCO}_{3}\) and non-volatile inert impurity on gentle heating loses \(5 \%\) of its weight due to reaction \(2 \mathrm{NaHCO}_{3} \longrightarrow \mathrm{Na}_{2} \mathrm{CO}_{3}+\mathrm{H}_{2} \mathrm{O}+\mathrm{CO}_{2}\). Residue is dissolved in water and formed \(100 \mathrm{~mL}\) solution and its 10 mL portion requires \(7.5 \mathrm{~mL}\) of \(0.2\ \mathrm{M}\) aqueous solution of \(\mathrm{BaCl}_{2}\) for complete precipitation of carbonates. Determine weight (in gram) of \(\mathrm{Na}_{2} \mathrm{CO}_{3}\) in the original sample.

  • Question 12
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    Which of the following has the lowest heat of hydrogenation per mole?

  • Question 13
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    Two elements \(\mathrm{A}\) and \(\mathrm{B}\) form compounds having formula \(\mathrm{AB}_{2}\) and \(\mathrm{AB}_{4} .\) When dissolved in \(20 \mathrm{~g}\) of benzene \(\left(\mathrm{C}_{6} \mathrm{H}_{6}\right), 1 \mathrm{~g}\) of \(\mathrm{AB}_{2}\) lowers the freezing point by \(2.3 K\) whereas \(1.0 \mathrm{~g}\) of \(\mathrm{AB}_{4}\) lowers it by \(1.3 \mathrm{~K}\). The molar depression constant for benzene is \(5.1 \mathrm{~K} \mathrm{~kg} \mathrm{~mol}^{-1}\). Calculate atomic masses of \(\mathrm{A}\) and \(\mathrm{B}\).

  • Question 14
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    Benzene can be conveniently converted into \(\mathrm{n}-\) propyl benzene by:

  • Question 15
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    Carbon tetrachloride has zero dipole moment because of ________.

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