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Chemistry Test - 4

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Chemistry Test - 4
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  • Question 1
    4 / -1

    Flint glass contains

    Solution

    Traditionally, flint glasses are lead glasses containing around 4-60% lead oxide.

  • Question 2
    4 / -1

    The reason for complex formation in d-block element is

    Solution

    The tendency of the transition metals to form complex ions is due to:

    (a) Small size of the metals ion

    (b) Large ionic or nuclear charge

    (c) Available d- orbitals

    (d) Low basicity of the metal ions

    (e) Availability of various oxidation state

    (f) High lewis acid nature of electron pair accepting tendency of the metal ion.

  • Question 3
    4 / -1

    The most important oxidation state of copper is

    Solution

    Cu(II) or the cupric ion is the most important oxidation state of copper. Cu(II) is the oxidation state of copper generally encountered in water. Cupric ions are coordinated with six water molecules in solution; the arrangement of the water molecules is distorted in that there are four molecules bound closely to the copper in a planar array while the other two are more loosely bound in polar position. Addition of ligands such as NH3 to the solution will successively displace only the four planar water molecules. Most cupric compounds and complexes are blue or green in color. They are frequently soluble in water.

  • Question 4
    4 / -1

    Which of the following co-ordination compounds would exhibit optical isomerism?

    Solution

    Tris (ethylenediamine) cobalt (III) bromide shows optical iso - merism.

    Two optical isomers are

    Two enantiomers (non - super - impossible mirror images)

    The molecule is chiral on the whole and exhibits optical isomerism.

  • Question 5
    4 / -1

    Acid catalysed hydration of alkenes except ethene leads to the formation of

    Solution

    For alkenes other then ethene, addition follows Markowinkov`s rule.

  • Question 6
    4 / -1

    A nitro group can be reduced to primary amino group by

    Solution

    A nitro (- NO2) group can be reduced to the corresponding amino (- NH2) group by treatment with a reducing metal such as tin or zinc in the presence of acid. Sodium bicarbonate is used to neutralize the acid from the first step. This two-step sequence is an important route to aniline.

  • Question 7
    4 / -1

    In the silver plating of copper, K[Ag(CN)2] is used instead of AgNO3. This is because

    Solution

    In the silver plating of copper, K[Ag(CN)2] is used instead of AgNO3. This is because of less availability of Ag+ ions as Cu cannot displace Ag from [Ag(CN)2]ion

  • Question 8
    4 / -1

    Which of the following conformations of butane is most unstable?

    Solution

    Fully eclipsed conformations of butane are most unstable as the groups attached to the two carbon atoms are closest to each other.

  • Question 9
    4 / -1

    Which of the following compounds is purified by steam distillation?

    Solution

    Aniline is purified by steam distillation.

  • Question 10
    4 / -1

    The correct order of bond energies of the following bonds is:

    (I) C(sp3)-C(sp3), (II) C(sp2)-C(sp2), (III) C(sp)-C(sp)

    Solution

    The sp hybridised orbital has 50% 's' character.

    The sp2 hybridised orbital has 33% 's' character.

    The sp3 hybridised orbital has 25% 's' character.

    Bond energy increases as the 's' character increases. 

    Hence, option (1) is correct.

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