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Structure of Atom Test - 6

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Structure of Atom Test - 6
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  • Question 1
    4 / -1

     

    Radial wave functio ns (R) of different orbitals are plotted. Which is/are correct graphs?

     

    Solution

     

     

    For 1s-orbital radial wave function (Ft) is maximum at r - 0, and falls rapidly as r increases thus, (a) correct.
    For2s-orbital, radial wave function (R) is maximum at (r = 0), falls to zero and further decreases with r. There appears radial nodes. Thus (b) correct.
    For2p-orbital, radial wave function is zero at r = 0, reaches maximum value (at r = a0) and then falls thus (c) is correct.

     

     

  • Question 2
    4 / -1

    For 2s-orbital electron, radial probability density R2 as function of r (distance) is given by

    Solution

    Correct Answer : b

    Explanation : (a) It represents R2 vs r for 1s

    (b) It represents R2 vs r for2s

    (c) It represents R2 vs r for 2p

  • Question 3
    4 / -1

    For an electron in 2p-orbital, radial probability function 4πr2R2 as a function of r is given by

    Solution

    (a) Describes radial wave function as a function of r for 1s
    (b) Describes radial probability function as a function of r for 2s
    (c) Describes radial wave function as a function r for 2s
    (d) Describes radial probability function as a function of r for 2p

  • Question 4
    4 / -1

    C onsider the following figures A and B indicating distribution of charge density (electron probability ) with distance r

    Select the correct statement(s). 

    Solution

    in case of 1s, falls as r increases thus, (A) is for 1s.
    In case of 2s, is maximum in the vicinity o f the nucleus, falls to zero giving spherical nodes and then rises to second highest value. Thus, (6) is for2s

  • Question 5
    4 / -1

    Select the correct statement(s).

    Solution

     Thus, is d e pendent on r true


    (b) and | | are dependent on r, θ and  : true
    (c) Angular wave function is determined by /land m, and not by n: true

  • Question 6
    4 / -1

    Which orbital gives an electron, a greater probability being found close to the nucleus?

    Solution

    3s is spherically symmetrical and its electron density is maximum at the nucleus. It decreases with r.

  • Question 7
    4 / -1

    Hamiltonian operator is the sum of two energy operators. These are

    Solution

    H = T + V


  • Question 8
    4 / -1

    Angular nodes in 4s- suborbit is equal to radial nodes in

    Solution

    Angular nodes in 4s = 0

  • Question 9
    4 / -1

    at any point is proportional to

    Solution

    Radial probability density = 4πr2 of find in g the electron within the volume of a very thin spherical shell at a distance r from nucleus.

  • Question 10
    4 / -1

    There is formation of in all five nodes (including terminal nodes) in a string of 12 cm. Thus, wavelength of the waves formed is 

    Solution

    For n nodes in a string

  • Question 11
    4 / -1

    For x -axis , wave function () can be written as

    Thus, Schrodinger wave equation along x-axis can be written as : 

    Solution



  • Question 12
    4 / -1

    The Schrodinger wave equation for H-atom is 

    where, a0 is Bohr’s radius. If radial node in 2s is at distance r0, then

    Solution



  • Question 13
    4 / -1

     

    The de Broglie wavelength associated with a ball of mass 200 g and moving at a speed of 5 metres/hour, is of the order of (h = 6.625 x 10-34 J s) is

     

    Solution

     

     

  • Question 14
    4 / -1

     

    What will be the wavelength of an electron moving with 1/10th of velocity of light?

     

    Solution


     

  • Question 15
    4 / -1

     

    Match the column I with column II and mark the appropriate choice.

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