Self Studies

Alcohols, Pheno...

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  • Question 1
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    The most appropriate reagents that can bring about the following transformation is

  • Question 2
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    Which major organic product is formed in the following reaction ?

  • Question 3
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    The major organic product formed in the reaction given below is

  • Question 4
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    In the following hydrolysis reactio, the major final product is

  • Question 5
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    In the reaction given below,

    The correct deduction concerning X and Y is

  • Question 6
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    An alkene on treatment with meta chloro perbenzoic acid undergoes epoxidation reaction to give oxirane. What is the correct order of increasing reactivity of the following in the above mentioned epoxidation reaction?

  • Question 7
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    Which of the following compound gives more than one oxirane upon epoxidation with Ag2O/heat? 

  • Question 8
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    The reaction given beiow that gives oxirane as the major organic product is

  • Question 9
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    Phenol is acidic due to resonance stabilization of its conjugate base :

  • Question 10
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    One of the constituents of baking powder is sodium hydrogencarbonate, the other constituent is

  • Question 11
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    What is the major product of following reaction

  • Question 12
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    Phenol on treatment with Phthalic anhydride gives:

  • Question 13
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    We can obtain picric acid from phenol by:

  • Question 14
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    Phenols do not respond to which of these tests?

  • Question 15
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    Comprehension Type

    Direction (Q. Nos. 15-17) This section contains a passage describing theory, experiments, data, etc. Two questions related to the paragraph have been given. Each question has only one correct answer out of the given 4 options (a), (b), (c) and (d).

    Passage

    Oxirane is a reactive ether, undergo nucleophilic attack at a-carbon in the presence of both acidic and basic medium. The generalised mechanism in the two medium are :

    I. Acidic medium

    II. Basic medium

    As shown above, in acidic medium, nucleophilic attack occur at more substituted α-carbon while in basic medium, nucleophilic attack occur preferably at less substituted α-carbon.

    Q. 

    In the reaction given below, th e final major organic product Y is

  • Question 16
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    Oxirane is a reactive ether, undergo nucleophilic attack at a-carbon in the presence of both acidic and basic medium. The generalised mechanism in the two medium are :

    I. Acidic medium

    II. Basic medium

    As shown above, in acidic medium, nucleophilic attack occur at more substituted α-carbon while in basic medium, nucleophilic attack occur preferably at less substituted α-carbon.

    Q. 

    If X is heated with concentrated H2SO4 a cyclic compound is formed which is

  • Question 17
    4 / -1

    Oxirane is a reactive ether, undergo nucleophilic attack at a-carbon in the presence of both acidic and basic medium. The generalised mechanism in the two medium are :

    I. Acidic medium

    II. Basic medium

    As shown above, in acidic medium, nucleophilic attack occur at more substituted α-carbon while in basic medium, nucleophilic attack occur preferably at less substituted α-carbon.

    Q. 

    What would be formed if 2-phenyloxirane is treated with CH3MgBr followed by acid hydrolysis?

  • Question 18
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    Direction (Q. Nos. 18-22) This section contains 5 questions. When worked out will result in an integer from 0 to 9 (both inclusive).

    Q. How many different ether isomers are possible for C3H6O ?

     

  • Question 19
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    Consider the reaction given below,

    Q.

    How many different triols isomers are formed?

     

  • Question 20
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    If propene undergoes oxidation to methyl oxirane, what is the net change in oxidation number of carbon atoms?

     

  • Question 21
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     In the following reaction,


    Q. 

    How many different stereoisomers of product formed ?

     

  • Question 22
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     How many different arene oxide would be formed on mono epoxidation of phenanthrene?

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