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States of Matter : Gases & Liquids Test - 6

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States of Matter : Gases & Liquids Test - 6
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  • Question 1
    4 / -1

     

    A sample of an ideal gas occupies 20 L under a pressure of 0.5 atm and under isothermal condition. On increasing its pressure to 1.0 atm, its volume will be

     

    Solution

     

     

    Since the system is isothermal, so temperature is constant.
    According to Boyle's lawP1V1= P2V2
    20×0.5=1×V2
    10=V2

     

     

  • Question 2
    4 / -1

    A 10.0 cm column of air is trapped by a column of Hg 4.00 cm long in a capillary tube of uniform bore when the tube is held horizontally at 1 atm. Length of the air column when the tube is held vertically with the open end up is

    Solution

    V1 = 10xcm³
    V2 = ?
    P1 = 1atm = 760mmHg
    P2 = (760 + 4)mmHg
    P1V1 = P2V2
    V2 = P1V1 / P2
    = 760 × 10x / 764
    = 9.5x
    Therefore,
    = 9.5x / x = 9.5

  • Question 3
    4 / -1

    Volume of an ideal gas is to be decreased by 10% by increase of pressure by x% under isothermal condition. Thus, x is

    Solution

    Applying Boyle 's law P1V1=P2V2 as temp is constant.
    So let initial pressure =P initial volume =V 
    Now final volume V2=V-10%of V =9V/10
    PV=P2×9V/10 so P2=10P/9
    Therefore increment in Pressure=P/9P×100%=100/9

  • Question 4
    4 / -1

    Density of an ideal gas at 298 K and 1.0 atm is found to be 1.25 kg m-3. Density of the gas at 1.5 atm and at 298 K is 

    Solution

    We know ideal gas equation,
    PV=nRT.
    n= m(mass)/M(molecular weight).
    PV=m/M RT.
    PM=m/v RT.
    density (d)=m(mass)/v (volume).
    PM=dRT.
    d=PM/RT.
    here, density is directly proportional to pressure and inversely proportional to temperature...
    d1/d2=P1 T2 / P2 T1.
    1.25/d2= 1×298/1.5×298.
    1.25/d2=1/1.5.
    d2= 1.25×1.5.
    d2=1.875

  • Question 5
    4 / -1

     

    An ideal gas is at 300 K and 1 atm. Then volume remains constant if

     

    Solution

     

     

    We know that
    pV = nRT 
    Or V = nRT/p
    If we increase both T and P 2 times, only then the volume remains constant.

     

     

  • Question 6
    4 / -1

    The pressure of a 1:4 mixture of dihydrogen and dioxygen enclosed in a vessel is one atmosphere. What would be the partial pressure of dioxygen?

    Solution

    Let the number of moles of dihydrogen and dioxygen be 1 and 4.

  • Question 7
    4 / -1

     

    At 298 K, which of the following gases has the lowest average molecular speed?

     

    Solution

     

    Under the same conditions the average kinetic energy of the gases should be equal.
    speed of gas1/speed of gas 2 = square root of (molar mass of gas2/molar mass of gas 1)
    So gases with small molar mass will move quicker
    eg speed of N2/speed of CO2 = sq. rt (44/28) = 1.25
    speed of N2/speed of F2 = sq rt. (38/28) = 1.16
    So order is N2, F2 and CO2
    then we concluded right ans. is (A)

     

  • Question 8
    4 / -1

    Charle's law defines value of 'k' as

    Solution

    According to Charles law,at constant pressure, V∝T
    Or V/T = k

  • Question 9
    4 / -1

     

    By what ratio will the average velocity of the molecules in a gas change when the temperature is raised from 50°C to 200°C?

    Solution

     

    This is the correct answer. If we take v200/v50, then we will get option b. But that is not according to the question.

     

  • Question 10
    4 / -1

    For Charles’ law, graphical representation between log V and log T under isobaric condition is shown below for equation V = kT.

    Q. Relation between p1, p2 and p3 is

     

    Solution

     

     

    From  ideal gas equation, we have
    pV = nRT
    Or V = nRT/p
    Taing log on both sides
    log V = log nRT - log p
    Or y = mx - c
    Let us make a point constant on time axis like this

    Now we have the temperature constant.So to have maximum value of log V, we need to have minimum value of log p. From the graph we can see that we have least pressure for p3 . So the order will be p3<p2<p1.

     

  • Question 11
    4 / -1

    For Charles’ law, graphical representation between log V and log T under isobaric condition is shown below for equation V = kT

     

    Q. Volume V = constant k, when

    Solution

    -272deg. 
    For C = 1 K
    V / 1 = K
    V = K

  • Question 12
    4 / -1

     

    Graphicaily Boyle’s law can be represented by various options depending on coordinates. Match the graphs in Column t with their coordinates in Column II and select the correct alternate from the codes given below.


     

     

    Solution

     

     

    From Boyle’s law;
    p ∝ 1/V ⇒ Graph i (Straight line passing through origin)
    Or pV = Constant ⇒ Graph ii (rectangular hyperbola)
    Taking log on both side;
    log(pV) = logK
    logp + logV = k’
    logp = -logV = k’ (y = -mx+c) ⇒ Graph iii
    log p = log V-1 + k’
    Logp = log(1/V) + k’ ⇒ Graph iv
    So option c is correct

     

     

  • Question 13
    4 / -1

     

    Direction (Q. Nos. 13 and 14) This section contains 2 questions. when worked out will result in an integer from 0 to 9 (both inclusive).

    Isothermally compressibility of an ideal gas is 

    Q. What is the value of a at 0.2 bar?

     

    Solution

     

    α = -1/V(dV/dP)T
    pV = RT;
    V = RT/p
    dV/dp = -RT/p2
    α = -1/(RT/p)×(-RT/p2)
    α = 1/p
    Or α =  (since p = 0.2)

     

  • Question 14
    4 / -1

     

    Cubic expansion coefficient (β) for an ideal gas is 

    Q. Its value at 250 K is x * 10-3 K -1. What is value of x?

     

    Solution

     

     

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