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Electrochemistr...

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  • Question 1
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    According to Faraday’s Second Law of Electrolysis the amounts of different substances liberated by the same quantity of electricity passing through the electrolytic solution are proportional:

  • Question 2
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    Charge on one mole of electrons i.e. one Faraday is approximately:

  • Question 3
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    In the primary batteries,

  • Question 4
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    A secondary cell after use ________ recharged by passing current through it in the ________ so that it can/can’t be used again.

  • Question 5
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    Fuel cells are _________ that are designed to convert the energy of combustion of fuels like hydrogen, methane, methanol, etc. directly into _________.

  • Question 6
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    In corrosion, a metal is _________ of electrons to oxygen and results in the formation of oxides.

  • Question 7
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    One of the simplest methods of preventing corrosion is to prevent the surface of the metallic object to come in contact with atmosphere. This can be done:

  • Question 8
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    An electrochemical method is to provide a sacrificial electrode of another metal (like Mg, Zn, etc.) which corrodes itself but saves the object. A typical example is

  • Question 9
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    Correct arrangement of Al, Cu, Fe, Mg and Zn in the order in which they displace each other from the solution of their salts is

  • Question 10
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    The standard emf of galvanic cell involving 3 moles of electrons in its redox reaction is 0.59 V. The equilibrium constant for the reaction of the cell is

  • Question 11
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    Emf of the cell 

    Mg (s) | Mg2+ (0.001M) || Cu2+ (0.0001M) | Cu(s)   at 298 K is

  • Question 12
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    Emf of the cell 

    Fe (s) | Fe2+ (0.001 M)|| H+ (1M)|H2 (g) (1 bar) |Pt(s)   at 298 K is

    (Given: Eocell ​= +0.44 V)

  • Question 13
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    The conductivity of 0.20 M solution of KCl at 298 K is 0.0248 S  cm-1. Calculate its molar conductivity. 

  • Question 14
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    The resistance of a conductivity cell containing 0.001M KCl solution at 298 K is 1500 Ω. What is the cell constant if conductivity of 0.001M KCl solution at 298 K is 0.146 × 10-3 S cm-1.

  • Question 15
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    How much charge is required for the reduction of 1 mol of Al3+ to Al?

  • Question 16
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    How much electricity in terms of Faraday is required to produce 40.0 g of Al from molten  Al2O3?

  • Question 17
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    Three electrolytic cells A, B, C containing solutions of ZnSO4, AgNO3 and CuSO4, respectively are connected in series. A steady current of 1.5 amperes was passed through them until 1.45 g of silver deposited at the cathode of cell. How long did the current flow? What mass of copper and zinc were deposited?  

  • Question 18
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    The standard emf of galvanic cell involving 3 moles of electrons in its redox reaction is 0.59 V. The equilibrium constant for the reaction of the cell is

  • Question 19
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    An increase in equivalent conductance of a strong electrolyte with dilution is mainly due to

  • Question 20
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    For the reduction of silver ions with copper metal the standard cell potential was found to be +0.46V at 25°C. The value of standard Gibbs energy, ΔG° wll be (F = 96500 C mol-1)

  • Question 21
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    Which of the following electrolytic solutions has the least specific conductance?

  • Question 22
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    The highest electrical conductivity of the following aqueous solutions is of

  • Question 23
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    The standard electrode potential is measured by

  • Question 24
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    When KMnO4 acts as an oxidizing agent and ultimately forms MnO42-, MnO2, Mn2O3, and Mn2+ then the number of electrons transferred in each case 

  • Question 25
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    On the basis of the following E° values, the strongest oxidizing agent is: 

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