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Hydrocarbons Test - 12

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Hydrocarbons Test - 12
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    Which of the following has the highest boiling point?

    Solution

    Benzonitrile has a greater dipole moment due to the greater bond polarity, and hence has a higher boiling point due to the dipole-dipole interactions.
    A) o-Xylene (144oC) group crowding
    B) Aniline (184oC) hydrogen bonding
    C) Benzonitrile (191oC) polarity
    D) Benzene (80.1oC) non-polar

     

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