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Alcohol, Phenol and Ether Test - 7

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Alcohol, Phenol and Ether Test - 7
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  • Question 1
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    Which of the following statements is/are correct regarding the preparation of ethers?

    Solution

    Alcohols undergo dehydration in the presence of protic acids (H2SO4, H3PO4). The formation of the reaction product, alkene or ether depends on the reaction conditions.

     

  • Question 2
    1 / -0

    Which of the following has approximately the same solubility in water as n-butyl alcohol?

    Solution

    Due to H-bonding between H2O and ether molecules, lower ethers such as dimethyl ether and ethyl methyl ether are completely miscible in water. The solubility of other lower ethers (i.e. diethyl ether) is comparable to that of corresponding alcohols (i.e. n-butyl alcohol). However, as the molecular mass increases, the solubility of ethers in H2O decreases due to a corresponding increase in the hydrocarbon portion of the molecule.

     

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