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Chemical Bonding and Molecular Structure Test - 5

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Chemical Bonding and Molecular Structure Test - 5
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  • Question 1
    1 / -0

    Which atom, when bonded to hydrogens, will not be sp3 hybridized at the central carbon?

    Solution

    Boron forms BH3, which is trigonal planar – the boron is sp2 hybridized.

     

  • Question 2
    1 / -0

    Which of the following statements are correct- 

    1) Bond order of NO =2.5 

    2) Bond order of NO+ =1

    3) Bond order of CO32- =1.75 

    4) Bond order of O2 =2

    Solution

    NO has (7+8) 15 electrons, and having bond order of 2.5 [as that of O2+ having 15 electrons] 

    bond order of O2 is 1/2 [10-6] =2

     

  • Question 3
    1 / -0

    Which one of the following has the strongest O-O bond?

    Solution

    bond order of O2+ is 1/2 [10-5] =2.5 

    bond order of O2 is 1/2 [10-6] =2 

    bond order of O2- is 1/2 [10-7] =1.5 

    Bond order of O22- is 1/2 [10-8] =1 

    Higher the bond order higher the bond dissociation energy and stronger the bond. 

    Among all, O2+ has strongest bond.

     

  • Question 4
    1 / -0

    If geometry is linear, trigonal planar and tetrahedral then unhybridized p orbital will have values?

    Solution

    The unhybridized p atomic orbitals are used to form π bonds. Two unhybridized p atomic orbitals each from a different atom overlap side to side, resulting in a shared electron pair occupying the space above and below the line joining the atoms (the internuclear axis).

     

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