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Chemistry Test 69

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Chemistry Test 69
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  • Question 1
    4 / -1

    [Co(H2O)6]2+ has three unpaired electrons and has a calculated value of magnetic moment as 3.87 BM, which is quite different from the experimental value of 4.40BM. This is due to:

    Solution

    Where n= Number of unpaired e

    As the t2g orbital is unsymmetrically filled.

    Thus, due to orbital motion contribution, the magnetic moment goes with the value 4.40BM.

    Hence, the correct option is (B).

     

  • Question 2
    4 / -1

    The increasing order of basicity of the following compounds is:

    Solution

     

  • Question 3
    4 / -1

    0.1 mole of N2O4( g) was sealed in a tube under one atmospheric conditions at 25C. Calculate the number of moles of NO2(g) present, if the Equlibrium N2O4(g) ⇌ 2NO2(g)(Kp=0.14) is reached after some time

    Solution

     

  • Question 4
    4 / -1

    Directions For Questions

    Two solutions of a substance (non electrolyte) are mixed in the following manner: 

    480 mL of 1.5M first solution +520 mL of 1.2M second solution.

    ...view full instructions

    What is the molarity of the final mixture?

    Solution

    For mixing solutions of same substances, final molarity is found using this formula.

     

  • Question 5
    4 / -1

    The molecular shapes of SF4, CF4 and XeFare:

    Solution

    SF4 (sp3d, trigonal bipyramidal with one equatorial position occupied by 1 lone pair), CF (sp3, tetrahedral, no lone pair), XeF4 (sp3d2, square planar, two lone pairs).

    Hence, the correct option is (D).

     

  • Question 6
    4 / -1

    Which of the following is an example of Baeyer-Villiger rearrangement?

    Solution

    The treatment of ketones with peracids (RCOOOH) or hydrogen peroxide gives esters by insertion of oxygen. The reaction is called Baeyer-Villiger rearrangement or Baeyer-Villiger oxidation.

    Hence, the correct option is (B).

     

  • Question 7
    4 / -1

    The percentage by volume of C3Hin a mixture of C3H8, CH4 and CO is 36.5. Calculate the volume of CO2 produced when 100ml of the mixture is burnt in excess of O2.

    Solution

     

  • Question 8
    4 / -1

    The species, having bond angles of 120° is:-

    Solution

    BCl3 is sp2 hybridized and is trigonal planar in shape and hence the bond angle is 120°.

    Hence, the correct option is (C).

     

  • Question 9
    4 / -1

    Hard water when passed through ion exchange resin containing R'COOH groups, becomes free from:

    Solution

    An ion exchange resin containing R - COOH group exchange cations like Ca2+, Mg2+, Na, Fe2+ with H+ when hard water is passed through it. This resin is called cation exchange resin.

     

  • Question 10
    4 / -1

    Chemical A is used for water softening to remove temporary hardness, A reacts with Na2CO3 to generate caustic soda. When CO2 is bubbled through A, it turns cloudy. What is the chemical formula of A?

    Solution

    The chemical A is calcium hydroxide (Ca(OH)2). It is used for water softening to remove temporary hardness. It reacts with sodium carbonate to form caustic soda.

     

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