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Chemistry Test 82

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Chemistry Test 82
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  • Question 1
    4 / -1

    When mercuric iodide is added to the aqueous solution of potassium iodide, the

    Solution

    HgI reacts with KI, to form K2​[HgI4​]. Due to this, the number of ions decreases thus decreasing the van't Hoff factor.

    ΔTf​ = i × kf​ × m

    Since ′i′ has decreased, it results in less depression in the freezing point causing the freezing point to rise.

    Hence, the correct option is (A).

     

  • Question 2
    4 / -1

    Which of the following sets represents copolymers only?

    Solution

    Glyptal, Buna S, Nylon 66, Dacron are copolymers because of the alternate chain.

    A copolymer is a polymer derived from more than one species of monomer. The polymerization of monomers into copolymers is called copolymerization. Copolymers obtained by copolymerization of two monomer species are sometimes called bipolymers.

    Hence, the correct option is (A).

     

  • Question 3
    4 / -1

    In a blast furnace, iron oxide is reduced to iron by

    Solution

    CO is used as a reducing agent. In the blast furnace, iron oxide is reduced by carbon.

    Iron is extracted from ores by using a blast furnace. Iron is available for many ore forms some of them are at the temperature of 1300oC, The carbon dioxide can be turned into carbon monoxide.

    At the temperature of, 

    And Carbon can be reduced from carbon monoxide.

    Hence, the correct option is (C).

     

  • Question 4
    4 / -1

    Which disease is caused by eating fish found in water contaminated with industrial waste having mercury?

    Solution

    Minamata disease is a disorder caused by methyl mercury poisoning that was first described in the inhabitants of Minamata Bay, Japan and resulted from their eating fish contaminated with mercury industrial waste.

    Hence, the correct option is (A).

     

  • Question 5
    4 / -1

    Arrange the following according to the increasing order of stability.

    P. CH3CH=CH2

    Q. cis-but-2ene

    R. trans-but-2ene

    S. 2,3-dimethylbut-2ene

    T. CH2=CH2

    Solution

    The order of stability of carbocation can also be explained by assuming that alkyl groups bonded to a positively charged carbon release electron density toward that carbon and help delocalize the positive charge on the cation. Thereby, the electron releasing ability of alkyl groups bonded to a cationic carbon is considered by two effects, inductive effect, and hyper-conjugation.

    S > R > Q > P > T is correct sequence
    Hence, the correct option is (D).

     

  • Question 6
    4 / -1

    Hexagonal crystal system is present in

    Solution

    The hexagonal crystal system consists of the 7 point groups that have a single six-fold rotation axis. These 7 point groups have 27 space groups (168 to 194), all of which are assigned to the hexagonal lattice system. Graphite ZnO and CdS is an example of a crystal that crystallizes in the hexagonal crystal system.

    Hence, the correct option is (A).

     

  • Question 7
    4 / -1

    The most harmful air pollutant produced by automobiles is

    Solution

    Automobiles emissions contribute to air pollution and are a major ingredient in the creation of smog in some large cities. Transportation contributes to more than half of the carbon monoxide, sulphur dioxide and nitrogen oxides, and almost a quarter of the hydrocarbons emitted into our air. Carbon monoxide (CO) is a colourless, odourless, toxic non-irritating gas. It is a product of incomplete combustion of fuel such as natural gas, coal or wood. Vehicular exhaust is a major source of carbon monoxide.

    Hence, the correct option is (D).

     

  • Question 8
    4 / -1

    Which of the following matches is/are not correct?

    1. Order of stability: O2> O> O2-

    2. Order of bond angle: H2S > NH3 > BF3 > SiH4

    3. Order of dipole moment: NH3 > PH3 > AsH3 > SbH3

    4. Order of covalent character: LiCl > NaCl > KCl > RbCl

    Solution

    The bond angle of H2S (Hydrogen sulfide) is 90 degrees. The bond of the angle of NH3 (Ammonia) is 107 degrees. The bond angle of BF3 (Boron trifluoride) is 120 degrees. The bond angle of SiH(Silicon hydride) is 109.5 degrees.

    Hence, the correct option is (B).

     

  • Question 9
    4 / -1

    Which of the following is formed when glycerol is heated with oxalic acid at 503K?

    Solution

    The glycerine is used in excess amounts and hence obtained in products also. But when it is heated with Oxalic acid at 503K, it gives allyl alcohol, i.e. those alcohols in which OH group attached to carbon is sp3 hybridized but the sp3 hybridized carbon is attached to sp2 hybridized carbon atom.
    Hence, the correct option is (C).

     

  • Question 10
    4 / -1

    According to VSEPR theory, the respective shapes of PCl5 and ICl5 should be

    Solution

    The molecular geometry of PCl5 is trigonal bipyramid with symmetric electron region distribution around the central atom.

    These are arranged in a trigonal bipyramidal shape with a 175° F(axial)-Cl-F(axial) bond angle. The two lone pairs take equatorial positions because they demand more space than the bonds. The result is a T-shaped molecule.
    Hence, the correct option is (A).

     

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