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  • Question 1
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    If 510 mg of a liquid on vapourisation in Victor Meyer's apparatus displaces 67.2 cm3 of air at STP, what is the molecular weight of the liquid?

  • Question 2
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    Directions: The following question has four choices out of which ONLY ONE is correct.

    Which one of the following aqueous solutions will exhibit the highest boiling point?

  • Question 3
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    van 't Hoff factor of BaCl2 at 0.01 M concentration is 1.98. What is the percentage of dissociation of BaCl2 at this concentration?

  • Question 4
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    Directions: Match the statements/expressions in Column – I with the statements/expressions in Column – II and indicate your answer by selecting the appropriate option. Any statement in Column – I can correctly match with one or more statement in Column – II.

    Column – I
    Column – II
    (A) Ideal solution (a) Raoult's law
    (B) Non-ideal solution (b) ΔH ≠ 0
    (C) Degree of dissociation of solute (c) Solutions with the same vapour pressure at a temperature
    (D) Isopiestic solution (d) ΔH = 0
    (e) Van't Hoff factor

  • Question 5
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    Which one of the following pairs of solution can we expect to be isotonic at the same temperature?

  • Question 6
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    Directions: The following question has four choices, out of which ONLY ONE is correct.

    If a 6.84% (wt/vol.) solution of cane sugar (mol. wt = 342) is isotonic with 1.52% (wt/vol.) solution of thiocarbamide, then the molecular weight of thiocarbamide is

  • Question 7
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    Ethylene dibromide (C2H4Br2) and 1,2-dibromopropane (C3H6Br2) form a series of ideal solutions over the whole range of compositions and at 85oC, the vapour pressures of these two pure liquids are 173 torr and 127 torr, respectively. If 10.0 g of ethylene bromide is dissolved in 80.0 g of 1,2-dibromopropane, then which of the following statements is correct?

  • Question 8
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    Match the following:

    Column I Column II
    (A) Positive deviation from Raoult's law (a) Osmotic pressure method
    (B) Addition of HgI2 to KI solution (b) Isotonic with human blood
    (C) Accurate method of determination of molar mass of a protein (c) Binary liquid mixtures
    (D) 0.9% NaCl solution (d) Elevation of freezing point of solution

  • Question 9
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    Two solutions of a substance are mixed in the following manner: 480 mL of 1.5 M first solution + 520 mL of 1.2 M second solution. What is the molarity of the final mixture?

  • Question 10
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    Benzene and toluene form nearly ideal solutions. At 293 K, the vapour pressure of benzene is 75 torr and that of toluene is 22 torr. The partial vapour pressure of benzene at 293 K in a solution containing 78 g of benzene and 46 g of toluene (in torr) is

  • Question 11
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    The elevation in boiling point of solution of 13.44 g of CuCl2 in 1 kg of water is (Kb = 0.52 K kg/mol)

  • Question 12
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    A 35.4 ml HCl is required for the neutralisation of a solution containing 0.275 g of sodium hydroxide. The normality of hydrochloric acid is

  • Question 13
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    A solution containing 10g per dm3 urea (molecular mass = 60gmol–1) is isotonic with a 5% solution of non volatile solute. The molecular mass of this non volatile solute is

  • Question 14
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    An aqueous solution of glucose is 10% in strength. What will be the volume in which 1 g mole of it is dissolved?

  • Question 15
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    A 0.100 m solution of NaClO3 freezes at - 0.343oC. At 0.001 m concentration of the same salt, the electrical interferences between the ions no longer exist, because on an average, the ions are too far from each other.

    The degree of dissociation of a 0.100 m NaCl solution is

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