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Organic Chemistry Some Basic Principles and Techniques Test - 16

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Organic Chemistry Some Basic Principles and Techniques Test - 16
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Weekly Quiz Competition
  • Question 1
    1 / -0
    In Lassaigne's method organic compound is fused with: 
    Solution
    $$N,S,$$ halogens and phosphorus present in  an organic compound are detected by Lassaigne's test, by fusing the compound with sodium $$(N_{a})$$ metal, which converts the elements present in the compound from covalent to ionic form.

    $$Na+C+N\overset{\Delta }{\rightarrow}NaCN$$

    $$2Na+S\overset{\Delta }{\rightarrow}Na_{2}S$$

    $$2Na+X\overset{\Delta }{\rightarrow}NaX\ (X=Cl, \ Br  \ or \ I)$$
  • Question 2
    1 / -0
    Neo-heptyl alcohol is correctly represented as :
    Solution
    For Neo-heptyl alcohol there should be two methyl branch on the second carbon of the chain along with alcohol group attached to a primary carbon atom. Thus option C is correct.

  • Question 3
    1 / -0
    Which of the following is branched chain alkane?
    Solution
    Isobutane is branched chain alkane.
    n-pentane and n-hexane are straight chain alkanes.
    Pyridine is heterocyclic aromatic compound.
  • Question 4
    1 / -0
    Common name of $$CH_{3}CH_{2}COOH$$ :
    Solution
    $$^{3}CH_{3}^{2}CH_{2}^{1}COOH \Rightarrow  $$ Propionic acid$$\Rightarrow $$ 3 corbons, so common name is
    common name $$\Rightarrow $$ propionic acid, IUAC $$\Rightarrow $$ Propanoic acid

  • Question 5
    1 / -0
    Homologue of $$C_{3}H_{4}$$ is:
    Solution
    A homologous series is a family of hydrocarbons with similar chemical properties that share the same general formula.

    The general formula of the compound in the question is $$C_n H_{2n-2}$$ with $$n=3$$.

    Only the compound in option $$A$$ satisfies the given general formula with $$n=4$$.

    So, homologue of $$C_3H_4$$ is $$C_4H_6$$.
  • Question 6
    1 / -0
    $$CH_{2}OHCHOHCH_{2}OH$$ is glycerol.
    It doesn't contain ___________ alcoholic group.
    Solution
    No $$3^{0}$$ -OH group
    $$\begin{matrix} 1^{ 0 } & CH_ 2 & - &OH  \\ & |&  &  \\2^0 & CH&-&OH\\&|&&\\3^0&CH_2&-&OH \end{matrix}$$
  • Question 7
    1 / -0
    Which of the following compounds has $$-OH$$ as a functional group?
    Solution
    In Butanone, the functional group is $$-C=O$$.
    In Butanoic acid, the functional group is $$-COOH$$.
    In Butanal, the functional group is $$-CHO$$.
    In Butanol, the functional group is $$-OH$$. 
  • Question 8
    1 / -0
    The functional groups present in the following compound is:
    $$CH_{3}   CH_{2}   CH_{2}   COOH$$
    Solution
    The functional group present in $$CH_{3}-CH_{2}-CH_{2}-COOH$$ is carboxylic acid, $$-COOH$$.
  • Question 9
    1 / -0
    IUPAC name of the compound 

    $$CH_2=CH - \underset{CH_2CH_3}{\underset{|}{C}H \,\,-}\,  \underset{Cl}{\underset{|}{C}} =CH_2$$
    Solution
    $$\overset{5}{C}H_2=\overset{4}{C}H - \underset{CH_2CH_3}{\underset{|}{\overset{3}{C}}H \,\,-} \,\, \underset{Cl}{\underset{|}{\overset{2}{C}}} =\overset{1}{C}H_2$$

    The correct IUPAC name is 2-Chloro- 3 ethyl-penta 1,4 -diene

    Option B is correct.
  • Question 10
    1 / -0
    Which of the following does not belong to the same homologous series ?
    Solution
    A, B & C are all saturated carbon compounds with the general formula: $$C_{n}H_{2n+2}$$, whereas $$C_{4}H_{8}$$ is an alkene with general formula $$C_{n}H_{2n}$$

    Option D is correct.
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