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Organic Chemist...

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  • Question 1
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    $$CH_3-\underset{Br}{\underset{|}{\overset{CH_3}{\overset{|}C}}}-CH_3, \, CH_3-\underset{Br}{\underset{|}{C}}-CH_3, \, CH_3-CH-Br$$
    Compare rate of $$E_2$$ reaction :

  • Question 2
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    Consider the following statements :
    (1) Bridgehead halides are inert towards both  $$S{_{N}}^{1}$$ and $$S{_{N}}^{2}$$ reactions (till one of the ring size is eight member ring)
    (2) The first step in both $$S{_{N}}^{1}$$ and $$E_1$$
    (3)   $$S{_{N}}^{2}$$ reaction proceed with total retention of configuration 
    (4)  $$E_2$$  elemnations are by use of asolvent of low polarity and high concentration of a strong base 
    Which og the above statements are correct?

  • Question 3
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    identify the rate of reaction of given compounds in $$E_2$$ reaction:

  • Question 4
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    In solvolysis of 1,2-dimethyl propyl p-tolunce sulfonate in acetic acid at $$75^{\circ}C$$, how many (alkane + substitution) products will be formed ?

  • Question 5
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    $$1.9 \times 10^{9}\ gm$$ of the metal having density $$19\ gm/ml$$ is dispersed in one litre of water to give a sol having spherical metal particles of raidus $$10\ nm.$$ The approximate number of metal sol particles per $$cm^{3}$$ of the sol is given by :

  • Question 6
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    Above conversion can be done by :

  • Question 7
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    In the given conversion best yield will obtained with.

  • Question 8
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    Product (E) is?

  • Question 9
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    $$CH_3CHO \overset{10 \, percent \,\, NaOH}{\underset{5^o C }{\longrightarrow}} \underset{\Delta}{\longrightarrow} \overset{H_2O}{\underset{Ni}{\longrightarrow}} (A) $$;
    Product (A) of the reaction is:

  • Question 10
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    Yield of each step as actually carried out in the laboratory is given. What is overall yield of reaction?

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