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Haloalkanes and...

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  • Question 1
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    I. $$CH_3CH_2I\xrightarrow[E2]{EtO^-} CH_2=CH_2+EtOH+I$$
    II. $$D_3C-CH_2I\xrightarrow[E2]{EtO^-}D_2C=CH_2+EtOD+I$$

    III. $$Me_3C-I\xrightarrow[SN^1 \ and\ E1]{EtO^-} Me_3C-OEt+(Me)_2C=CH_2$$

    IV. $$(CD_3)_3C-I\xrightarrow[SN^1 and\ E1]{EtO^-}(CD_3)_3C-OEt+(CD_3)_2C=CD_2$$
    Consider the given reactions.
    Which of the following statement(s) is/are correct?

  • Question 2
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    In the given reactions, the rate of reaction of $$(I)$$ and $$(II)$$ are same. Both reactions proceed by which mechanism?

  • Question 3
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    Which of the given mentioned positions in the given compound is more reactive towards electrophilic substitutions?

  • Question 4
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    In the reaction $${CH}_{3}C\equiv  \overset { \oplus  }{ CNa } +{ \left( { CH }_{ 3 } \right)  }_{ 2 }CHCl\longrightarrow  $$ the product formed is:

  • Question 5
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    Compounds $$(B)$$ and $$(C)$$ respectively are :

  • Question 6
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    Which of the following synthesis could not be done without involving blocking position on the ring?

  • Question 7
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    In the given reactions, the rate of reaction of $$(I)$$ is faster than that of $$(II)$$. By which mechanism do both reactions proceed?

  • Question 8
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    Choose the incorrect reaction.

  • Question 9
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    Consider the following anions.
    When attached to $$sp^{3-}$$ hybridized carbon, their leaving group ability in nucleophilic substitution reactions decreases in the order.

  • Question 10
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    The yield of chlorobenzene obtained by reaction of phenols with $$P{Cl}_{5}$$ is less, due to the formation of :

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