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Alcohols Phenols and Ethers Test - 16

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Alcohols Phenols and Ethers Test - 16
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  • Question 1
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    Assertion: Addition reaction of water to but-1-ene in acidic medium yields butan-1-ol. 

    Reason : Addition of water in acidic medium proceeds through the formation of primary carbocation.

    Solution

    Addition reaction of water to but-1-ene in acidic medium yields butan-2- ol.

    Addition of water in acidic medium proceeds through the formation of a secondary carbocation.

     

  • Question 2
    1 / -0

    Assertion: p-nitrophenol is more acidic than phenol.

    Reason: Nitro group helps in the stabilisation of the phenoxide ion by dispersal of negative charge due to resonance.

    Solution

    P-nitro phenol is more acidic as nitro group helps in the stabilization of the phenoxide ion by dispersal of negative charge due to resonance.

     

  • Question 3
    1 / -0

    Assertion : Boiling points of alcohols and ethers are high.

    Reason : They can form intermolecular hydrogen-bonding.

    Solution

    Boiling points of alcohols are higher than that of ethers of comparable molecular mass.

    Alcohols can form intermolecular hydrogen bonding while ethers cannot.

     

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