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Stoichiometry and Redox Reactions Test - 2

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Stoichiometry and Redox Reactions Test - 2
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  • Question 1
    1 / -0

    Chromium has the highest oxidation state in

    Solution

    Oxidation state of chromium in CrO3 is +6.

    Oxidation state of chromium in CrF3 is +3.

    Oxidation state of chromium in Cr2Ois +3.

    Oxidation state of chromium in CrF5 is +5.

    Oxidation state of chromium in CrClis +4.

    Hence, chromium has the highest oxidation state in CrO3.

     

  • Question 2
    1 / -0

    For the reaction between KMnO4 and H2O2, the number of electrons transferred per mole of H2O2 is

    Solution

    KMnO4 is a stronger oxidising agent than H2O2 in the acidic, basic as well as neutral mediums.
    In the neutral medium,

    2KMnO+ 3H2O2  2MnO2 + 2KOH + 2H2O + 3O2

    The overall equation involves a transfer of 6 electrons.

    Therefore, the number of electrons transferred per mole of H2O2 is 2 and the number of electrons transferred per mole of KMnO4 is 3.

     

  • Question 3
    1 / -0

    In standardisation of Na2S2O3, using K2Cr2O7 by iodometry, the equivalent weight of K2Cr2O7 is

    Solution

    Cr2O72- + 14H+ + 6e→ 2Cr3+ + 7H2O

    Eq. wt. of K2Cr2O7 = 1/6 × (molecular weight)

     

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