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HaloAlkanes & HaloArenes Test - 1

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HaloAlkanes & HaloArenes Test - 1
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  • Question 1
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    Statement-1: 1-Chlorobutane on heating with alcoholic KOH undergoes dehydrohalogenation to yield 1-butene as the major product.

    Statement-2: The reaction does not occur through carbocation intermediate but instead occurs by a concerted mechanism.

    Solution

    Statement-2 correctly explains Statement-1.

  • Question 2
    1 / -0

    The C-I bond (in CH3CH2CH2I )is formed by the overlapping of ____.

    Solution

    Carbon belongs to 2nd period, while iodine belongs to 5th period, hence the C-I bond in CH3CH2CH2I must be formed by the overlapping of 2sp3orbital of C with the 5pz orbital of iodine.

     

  • Question 3
    1 / -0

    Although hexafluoroethane (C2F6, b.p. - 79°C) and ethane (C2H6, b.p. - 89°C) differ very much in their molecular weights, their boiling points differ only by 10°C. This is due to

    Solution

    Small difference in boiling points of C2F6 and C2H6 is due to the fact that (i) the F aton is only slightly larger than H, and (ii) F has low polarizability

  • Question 4
    1 / -0

    Statement-1: Grignard reagents are prepared in ethers but not in benzene.

    Statement-2: Grignard reagents are soluble in benzene.

    Solution

    The correct reason is: Grignard reagents are soluble in ether but not in benzene.

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