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Chemistry Test ...

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  • Question 1
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    Which of the following statements about standard enthalpy of formation (ΔfH) is correct?

  • Question 2
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    If the standard Gibbs energy change (ΔG) for a reaction is 10 kJ/mol at 298 K, what is the value of the equilibrium constant K?

  • Question 3
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    For a reaction with  ΔG∘ = −25 kJ/mol at 298 K, what can be inferred about the equilibrium constant K?

  • Question 4
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    A chemist has four bottles, each containing a pure monocarboxylic acid of formula CH16 O2. The acids are (i) 2-ethyl-2-methylhexanoic acid, (ii) 2,2,3-trimethylpentanoic acid, (iii) 2,2-dimethyl-3-ethylbutanoic acid, and (iv) 3,3-dimethyl-2-ethylbutanoic acid. She performs two reactions with each acid: (A) decarboxylation with soda-lime at 630 K, and (B) HVZ bromination followed by treatment with aqueous KHCO3. For which acid will the total mass of the organic product(s) obtained from reaction A equal exactly 0.500 times the mass of the organic product(s) obtained from reaction B when both reactions start with 1.00 g of the acid? (Assume 100 % yield and no loss of material; treat any stereoisomeric mixture as a single species.)

  • Question 5
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    Which reaction is used to distinguish primary, secondary, and tertiary amines?

  • Question 6
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    The complex [Co(NH3)5(NO2)](NO3)2 can exhibit which type of isomerism?

  • Question 7
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    Freon-12 (CCl2F2) is manufactured from tetrachloromethane via the Swarts reaction. What is the primary industrial use of Freon-12?

  • Question 8
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    Conductance of   0.1 M KCl (conductivity =  X ohm−1 cm−1) filled in a conductivity cell is  Y ohm−1.
    If the conductance of 0.1 M NaOH filled in the same cell is  Z ohm−1, the molar conductance of NaOH will be:

  • Question 9
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    At 20C, the Ag+ ion concentration in a saturated solution of Ag2CrO4 is  1.5 × 10−4 mole/litre.

    At 20C, the solubility product of Ag2CrO4 would be:

  • Question 10
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    The solubility product of  AgCl  is 1.44 × 10−4 at 100oC . The solubility of silver chloride in boiling water may be

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