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Aldehydes And Ketones Test - 13

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Aldehydes And Ketones Test - 13
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  • Question 1
    1 / -0

    Which of the following will not undergo Cannizaro reaction?

    Solution

    Only the aldehydes that do not have any α-hydrogen undergo Cannizaro reaction (disproportionation) in the presence of a strong alkali.

    CH3CHO (acetaldehyde) has three α-hydrogens.

    Hence, acetaldehyde will not undergo disproportionation in the presence of a strong alkali.

     

  • Question 2
    1 / -0

    Write the following acids in the decreasing order of acidic strength?

    (i) Oxalic acid
    (ii) Acetic acid
    (iii) Succinic acid

    Solution

    Dicarboxylic acids are more acidic than the monocarboxylic acids.
    Oxalic acid is more acidic than succinic acid as there is no +I effect from the alkyl groups.

     

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